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## How Much Work Can One Molecule Do?

There are many misconceptions about how atmospheric processes work, and one that often seems to present a mental barrier is the idea of How much work can one molecule do?

This idea – presented in many ways – has been a regular occurence in comments here and it also appears in many blogs with eloquent essays on the “real role” of CO2 in the atmosphere, usually unencumbered by any actual knowledge of the scientific discipline known as physics.

Well, we all need mental images of how invisible or microscopic stuff really works.

When we consider CO2 (or any trace gas) absorbing longwave radiation the mental picture is first of trying to find a needle in a haystack.

And second, we found it, but it’s so tiny and insignificant it can’t possibly do all this work itself?

How much can one man or woman really do?

### Finding a Needle in a Haystack

Think of a beam of energy around 15.5μm. Here is the graph of CO2 absorption around this wavelength. It’s a linear plot so as not to confuse people less familiar with log plots. Water vapor is also plotted on this graph but you can’t see it because the absorption ability of water vapor in this band is so much lower than CO2.

CO2 absorption, 15.4-15.6um, linear, from spectralcalc.com

The vertical axis down the side has some meaning but just think of it for now as a relative measure of how effective CO2 is at each specific wavelength.

Here’s the log plot of both water vapor and CO2. You can see some black vertical lines – water vapor – further down in the graph. Remember as you move down each black horizontal grid line on the graph the absorption ability is dropping by a factor of 100. Move down two black grid lines and the absorption ability has dropped by a factor of 10,000.

CO2 absorption - log graph - 15.4-15.6um, from spectralcalc.com

Now, I’ll add in the absorption ability of O2 and N2 – the gases that make up most of the atmosphere – check out the difference:

Spectralcalc wouldn’t churn anything out – nothing in the database.

15.5μm photons go right through O2 and N2 as if they didn’t exist. They are transparent at this wavelength.

So, on our needle in the haystack idea, picture a field – a very very long field. The haystacks are just one after the other going on for miles. Each haystack has one needle. You crouch down and look along the line of sight of all these haystacks – of course you can only see the hay right in front of you in the first one.

Some magic happens and suddenly you can see through hay.

Picture it..  Hay is now invisible.

Will you be able to see any needles?

That’s the world of a 15.5μm photon travelling up through the atmosphere. Even though CO2 is only 380ppm, or around 0.04% of the atmosphere, CO2 is all that exists for this photon and the chances of this 15.5μm photon being absorbed by a CO2 molecule, before leaving this world for a better place, is quite high.

In fact, there is a mathematical equation which tells us exactly the proportion of radiation of any wavelength being absorbed, but we’ll stay away from maths in this post. You can see the equation in CO2 – An Insignificant Trace Gas? Part Three. And if you see any “analysis” of the effectiveness of CO2 or any trace gas which concludes it’s insignificant, but doesn’t mention this equation, you will know that it is more of a poem than science. Nothing wrong with a bit of poetry, if it’s well written..

Anyway, it’s just a mental picture I wanted to create. It’s not a perfect mental picture and it’s just an analogy – a poem, if you will. If you want real science, check out the CO2 – An Insignificant Trace Gas Series.

### CO2 – The Stakhanovite of the Atmospheric World?

Back in the heady days of Stalinist Russia a mythological figure was created (like most myths, probably from some grain of truth) when Aleksei Stakhanov allegedly mined 14 times his quote of coal in one shift. And so the rest of the workforce was called upon to make his or her real contribution to the movement. To become Stakhanovites.

This appears to be the picture of the atmospheric gases.

Most molecules are just hanging around doing little, perhaps like working for the _____ (mentally insert name of least favorite and laziest organization but don’t share – we try not to offend people here, except for poor science)

So there’s a large organization with little being done, and now we bring in the Stakhanovites – these champions of the work ethic. Well, even if they do 14x or 100x the work of their colleagues, how can it really make much difference?

After all, they only make up 0.04% of the workforce.

But this is not what the real atmosphere is like..

Let’s try and explain how the atmosphere really works, and to aid that process..

### A Thought Experiment

For everyone thinking, “there’s only so much one molecule can do”, let’s consider a small “parcel” of the atmosphere at 0°C.

We shine 15.5μm radiation through this parcel of the atmosphere and gradually wind up the intensity. Because it’s a thought experiment all of the molecules involved just stay around and don’t drift off downwind.

The CO2 molecules are absorbing energy – more and more. The O2 and N2 molecules are just ignoring it, they don’t know why the CO2 molecules are getting so worked up.

What is your mental picture? What’s happening with these CO2 molecules?

a) they are just getting hotter and hotter? So the O2 and N2 molecules are still at 0°C and CO2 is at first 10°C, then 100°C, then 1000°C?

b) they get to a certain temperature and just put up a “time out” signal so the photons “back off”?

c) other suggestions?

### The Real Atmosphere – From Each According to His Ability, To Each According to His Need

What is the everyday life of a molecule like?

It very much depends on temperature. The absolute temperature of a molecule (in K) is proportional to the kinetic energy of the molecule. Kinetic energy is all about speed and mass. Molecules zing around very fast if they are at any typical atmospheric temperature.

Here’s a nice illustration of the idea (from http://www.chem.ufl.edu/~itl/2045/lectures/lec_d.html).

At sea level, a typical molecule will experience around 1010 (10 billion) collisions with other molecules every second. The numbers vary with temperature and molecule.

Think of another way – at sea level 8×1023 molecules hit every cm2 of surface per second.

Every time molecules collide they effectively “share” energy.

Therefore, if a CO2 molecule starts getting a huge amount of energy from photons that “hit the spot” (are the right wavelength) then it will heat up, move even faster, and before it’s had time to say “¤” it will have collided with other molecules and shared out its energy.

This section of the atmosphere heats up together. CO2 can keep absorbing energy all day long even as a tiny proportion of the molecular population. It takes in the energy and it shares the energy.

If we can calculate how much energy CO2 absorbs in a given volume of the atmosphere we know that will be the energy absorbed by that whole volume of atmosphere. And therefore we can apply other well-known principles:

• heating rates will be determined by the specific heat capacity of that whole volume of atmosphere
• re-radiation of energy will be determined by the new temperature and ability of each molecule to radiate energy at wavelengths corresponding to those temperatures

### Conclusion

The ability of a CO2 molecule to be “effective” in the atmosphere isn’t dependent on its specific heat capacity.

Molecules have embraced “communism” – they share totally, and extremely quickly.

Update – New post on the related topic of understanding the various heat transfer components at the earth’s surface – Sensible Heat, Latent Heat and Radiation

## CO2 in the Solar Spectrum

If CO2 absorbs incoming solar radiation then surely an increase in CO2 will reduce incoming radiation and balance any increase in longwave radiation.

The important factor is the usual question of quantifying the different effects.

Let’s take a look.

CO2 absorption in the 0.17-5um band, with solar spectrum overlaid

The CO2 absorption spectrum is from the line list browser of the recommended spectralcalc.com. The line list only goes down to 0.17μm (170nm), hence the reason for the graph not starting at 0.0μm.

The solar radiation is overlaid. Well, more accurately, the Planck function for 5780K is overlaid (simply drawn using Excel). Note that the CO2 absorption spectrum is on a log graph, while the radiation is on a linear graph. For those not so familiar with logarithmic graphs, the peak absorption around 4.3μm is 10-18, while the two peak absorptions just below 1μm are at 10-26 – which is 100,000,000 less.

The value of seeing the solar radiation spectrum overlaid is it enables you to see the relative importance of each absorption area of CO2. For example, the solar radiation between 2 – 4μm is only 5% of the solar radiation, so any absorption by CO2 will be quite limited.

Here’s the comparison with the important 15μm band of CO2. A 6μm width is shown, overlaid (blue line) with the 12-18um longwave radiation of a 288K (15°C) blackbody:

CO2 absorption in the 12-18um band, with terrestrial spectrum overlaid

Just a little explanation of this graph and how to compare it to the solar version.

The average surface temperature of the earth is 15ºC, and it emits radiation very close to blackbody radiation (watch out for a dull post on Emissivity soon).

The proportion of radiation of a 288K blackbody between 12-18μm is 28%. What we want to do is enable a comparison between the CO2 absorption of solar radiation and terrestrial radiation.

Averaged across the globe and the year the incoming solar radiation at the top of atmosphere (TOA) is 239 W/m2 and the radiation from the earth’s surface is 396 W/m2. This works out to 65% higher, but so as not to upset people who don’t quite believe the earth’s surface radiation is higher than incoming solar radiation I simply assumed they were equal and scaled this section of the earth’s terrestrial radiation to about 28% of the solar radiation on the earlier graph. We are only eyeballing the two graphs anyway.

So with this information digested, the way to compare the two graphs is to think about the absorption spectra of CO2 simply being scaled by the amount of radiation shown overlaid in both cases.

As you can see the amount of absorption by CO2 of solar radiation is a lot less than the absorption of longwave radiation. Remember that we are looking at the log plot of absorption.

### Is That the Complete Story?

Really, it’s more complicated, as always with atmospheric physics. There’s nothing wrong with taking a look at the approximate difference between the two absorption spectra, but luckily someone’s already done some heavy lifting with the complete solution to the radiative transfer equations using line by line calculations. For more on these equations, see the CO2 – An Insignificant Trace Gas series, especially Part Three, Four and Five.

The paper with the heavy lifting is Radiative forcing by well-mixed greenhouse gases: Estimates from climate models in the IPCC AR4 by W.D. Collins (2006). There’s a lot in this paper and aspects of it will show up in the long awaited Part Eight of the CO2 series and also in Models, On – and Off, the Catwalk.

Solving these equations is important because we can look at the absorption spectrum of CO2 in the 15μm band, but then we have to think about the absorption already taking place and what change in absorption we can expect from more CO2. Likewise for the solar spectrum.

Here are the two graphs, which include other important trace gases, as well as the impact of a change in water vapor. Note the difference in vertical axis values – the forcing effect of these gases on solar radiation has to be multiplied by a factor of 1000 to show up on the graph. The blue lines are CO2.

Net absorption of solar radiation by various "greenhouse" gases

Longwave radiative forcing from increases in various "greenhouse" gases

You can also see that the CO2 absorption in shortwave is across quite narrow bands (as well as being scaled a lot lower than terrestrial radiation) – therefore the total energy is less again. The vertical scale is energy per μm..

From these calculations we can see that with a doubling of CO2 there will be a very small impact on the radiation received at the surface, but a comparatively huge increase in longwave radiation retained – “radiative forcing” at the tropopause (the top of the troposphere at 200mbar).

### So Is That the Complete Story?

Not quite. If trace gases in the atmosphere absorb solar radiation, is that so different from the surface absorbing solar radiation?

Or to put it another way, if the radiation doesn’t strike the ground, where does it go? It’s still absorbed into the climate system, but in a different location (somewhere in the atmosphere).

But as one commenter said:

The other point [this one] you make is simply not true and/or also not proven. There is only so much energy that can be taken up by a molecule.

This is a theme that has arrived in various comments from various posts. So the concept of How much work can one molecule do? is worth exploring in a separate post.

Hopefully, it’s clear from what is presented here that increases in CO2 absorption of the solar radiation are very small compared with absorption of longwave radiation.

## American Thinker Smoking Gun – Gary Thompson’s comments examined

### Recap

This post is a follow on from my original article: American Thinker – the Difference between a Smoking Gun and a Science Paper.

Gary Thompson who wrote the article in American Thinker that prompted my article was kind enough to make some comments and clarifications. Instead of responding in the comments to the first article, I thought it was worth a new post, especially to get the extra formatting that is allowed in posts rather than comments.

I appreciate him commenting and I’m sure he has a thick skin, but just in case, any criticisms are aimed at getting to the heart of the matter, rather than at him – or anyone else who has different views.

For people who have landed at this post and haven’t read the original.. the heart of Gary’s article were 3 papers, of which I examined one (the first). The paper compared two 3-month periods 27 years apart in the East and West Pacific. Gary commented that the actual OLR (outgoing longwave radiation) was higher in the later period in the important CO2 band (or what we could see of it).

His claim – the theory says that more CO2 should lead to less emission at those wavelengths and therefore the theory has been disproved.

My point – Gary doesn’t understand the theory. The temperature was higher in the later period in this region and therefore the radiation leaving the earth’s surface would be higher. We’ll see this explained again, but did I mention that you should read Gary’s article and my article before moving forward? Also at the end of the Science of Doom post you can see Gary’s comments. Always worth reading what people actually wrote rather than what someone (me) with the opposite point of view highlighted from their words..

### The Unqualified Statements in Papers

Gary started by saying:

I know why the authors of the papers were using climate models to simulate the removal of effect from surface temperatures and humidity and that the ‘theory’ says you must do that. But my problem lies in two peer reviewed papers that casts doubt on that theory and that method.

And cites two papers. The first, a 1998 paper: The Trace Gas Greenhouse Effect and Global Warming by the great V. Ramanathan (I will continue to call him ‘great’ even though he didn’t reply to my email about his 1978 paper.. possibly busy, but still..).

I recommend this 1998 paper to everyone reading this article. Even though it is 12 years old, it is all relevant and a very readable summary.

### The Great Ramanathan

Gary pointed out page 3 where statements appeared to back up his (Gary’s) interpretation of the later OLR study. Here’s what Ramanathan said:

Why does the presence of gases reduce OLR? These gases absorb the longwave radiation emitted by the surface of the earth and re-emit to space at the colder atmospheric temperatures. Since the emission increases with temperature, the absorbed energy is much larger than the emitted energy, leading to a net trapping of longwave photons in the atmosphere. The fundamental cause for this trapping is that the surface is warmer than the atmosphere; by the same reasoning decrease of temperature with altitude also contributes to the trapping since radiation emitted by the warmer lower layers are trapped in the regions above.

By deduction.. an increase in a greenhouse gas such as CO2 will lead to a further reduction in OLR. If the solar absorption remains the same, there will be a net heating of the planet.

Gary commented on the last part of this:

Notice there is no clarifying statement about having to use model simulated graphs to ‘correct’ for surface temperatures and water vapor before seeing that OLR reduction.

And on the first part:

“since the emission increases with temperature, the absorbed energy is much larger than the emitted energy, leading to a net trapping of longwave photons in the atmosphere.” – here the author stated clearly that even taking into account higher emissions from warmer surfaces, the net will still be a reduction.

For half the readers here, they are shaking their heads.. But for Gary and the other half of the readership, let’s press on.

First of all, if we took any of 1000 papers on the “greenhouse” effect and observations, models, theoretical adjustments, impacts on GCMs – I bet you could find at least 700 – 900 of them at some point will make a statement that could be pulled out which has no “clarifying statement”. That “cast doubt” on the theory. Perhaps 1000 out of a 1000.

Context, context, context as they say in real estate.

Where to begin? Let’s look at “the theory” first. And then come back and examine Ramanathan’s statements.

### The Theory

There are a few basics. For newcomers, you can take an extended look at the theory in CO2 – An Insignificant Trace Gas? It’s in seven parts! Actually it’s a compressed treatment.

This is itself is a clue.

In the books I have seen on Atmospheric Physics many tens of pages are devoted to radiation, including absorption and re-radiation – the “greenhouse” effect – and many tens of pages are devoted to convection. Understanding the basics is critical.

For Gary and his followers, the theory is on a precipice and these papers are giving us that clue. For people who’ve studied the subject the theory of the “greenhouse” effect is as solid as the theory of angular momentum, or the 2nd law of thermodynamics (the real one, not the imaginary one).

As Ramanthan says in the same paper Gary cites:

It is convenient to separate the greenhouse effect from global warming. The former is based on observations and physical laws such as Planck’s law for black-body emission. The concept of warming that results from the greenhouse effect, is based on deductions from sound physical principles. Numerous feedback processes, determine the magnitude of the warming; these feedbacks are treated with varying degrees of sophistication in GCMs and other climate models. As a result, predictions of the magnitude of the warming are not only model dependent but are subject to large uncertainties..

If I can paraphrase:

Greenhouse effect – dead solid. Global warming – lots of factors, need GCMs, pretty complicated.

Perhaps he has not realized that his words in the same paper combined with experiments demonstrate a flaw in the theory of the dead-solid “greenhouse” effect..

Back to the theory, but first..

### A Quick, possibly Annoying, Diversion to the Theory of Gravity

But before we start, I thought it was worth an analogy. Analogies are illustrations, not proof of anything. They can often inflame an argument, but that’s not the intention here. Many people who are still undecided about the amazing theory of the inappropriately-named “greenhouse” effect might welcome a break from thinking about it.

The theory of planetary movements is my analogy. I picture a world where gravity – and its effects on the planets orbiting the sun – is strangely controversial. A concerned citizen, leafing through some fairly recent scientific papers notices that planets don’t really go around the sun in ellipses as the theory claims. In fact, there are some quite odd movements. And so, surprised that the scientists can’t see what’s in plain sight, this citizen draws attention to them.

When some detail-orientated commenters point out that the theory is actually (in part):

F = GMm/r2

where F= force between 2 bodies, G is a constant, M and m are the masses of the 2 bodies and r is the distance between them

And the ellipse idea is just a handy generalization of the results of the laws of graviational attraction.

And the reason why some planetary movements recently measured don’t follow an ellipse is because a few planets are a bit closer together, there’s a large asteroid flying between them and so when we do the maths it all works out pretty well.

The original concerned citizen then pulls out a few papers where, in the introduction, gravity is explained as that force that produces elliptical movements in the planets.. with no disclaimers about F=GMm/r2 and claims that this theory is, therefore, under question.

Why this annoying analogy? Most “theories” in physics are developed because of some observations which get analyzed to death – and finally someone produces a “comprehensive theory” that satisfies most of the relevant scientific community. The paper with the comprehensive theory usually contains some equations, some observations, some matching of the two – but often in common everyday usage the shorthand version of the theory is used.

“The theory of gravity tells us that planets orbit the sun in an elliptical manner, and ..”

So much more tedious to keep saying F=GMm/r2, and the other formulae..

(I know, I haven’t proved anything, but maybe a few readers can take a moment and see a parallel..)

### Back to the Radiative-Convective Theory

First, bodies radiate energy according to Planck’s formula, which looks complicated when written down. The idea is simplified by the total energy radiated according to the Stefan-Boltzmann law which says that total energy is proportional to the 4th power of temperature.

Temperature goes up, energy radiated goes up (quite a bit more) – and the peak wavelength is a little lower. Here’s a graphical look of the Planck formula which takes away the mathematical pain:

Blackbody Radiation at 288K and 289K (15'C and 16'C)

Two curves – 288K and 289K. Now zoomed in a little where most of the energy is:

Close up of the peak energy of 288K and 289K

Total energy in the top curve (289K) is 396W/m^2, and in the bottom curve (288K) is 390W/m^2

Second, trace gases absorb energy according to a formula, which when simplifed is the Beer-Lambert law.

Absorption of Radiation as "optical thickness" increases

Without going into a lot of maths, as the concentration of a “greenhouse” gas increases, the absorption graph falls off more steeply – more energy is absorbed.

Third, re-radiation of this energy takes place according to an energy balance equation that you can see in CO2 – Part Three. The energy balance or radiative transfer equations rely on knowledge of the temperature profile in the lower atmosphere (the troposphere), because the actual temperature here is dominated by convection not radiation. (Radiation still takes place and the temperature profile is a major factor in the radiation – but this effect is not the primary determinant of the temperature profile).

When Gary says:

I know why the authors of the papers were using climate models to simulate the removal of effect from surface temperatures and humidity and that the ‘theory’ says you must do that. But my problem lies in two peer reviewed papers that casts doubt on that theory and that method.

It sounds like Gary believes this “model” is some suspicious extra that tries to deal with problems between the theory and the real world. But it’s the foundation. Anyone who had read an introduction to atmospheric physics would understand that. Someone who had tried hard to understand a few papers without a proper foundation would easily miss it.

• Higher temperatures increase OLR
• More trace gases reduce OLR in certain wavelengths

Which effect dominates in a particular situation?

It’s simple conceptually. But, if we want to find out exact results – such as, which effect dominates in a particular situation – we need a “model” = an equation or set of equations. Because if we want to quantify the effects we have to solve some tricky equations which you can see in a paper by.. the Great Ramanathan. Well, Ramanathan & Coakley 1978  – a seminal paper on Climate Modeling through Radiative-Convective Models, here’s an extract from p7:

A few equations from Ramanathan and Coakley, p7

Lots of maths. The rest of the paper is similar. Let’s move on to Ramanathan’s much later paper and what he said and meant.

### Has Ramanathan given up on The Theory?

Let’s review the words Gary pulled out of the paper:

Why does the presence of gases reduce OLR? These gases absorb the longwave radiation emitted by the surface of the earth and re-emit to space at the colder atmospheric temperatures. Since the emission increases with temperature, the absorbed energy is much larger than the emitted energy, leading to a net trapping of longwave photons in the atmosphere.

Gary reads into this “here the author stated clearly that even taking into account higher emissions from warmer surfaces, the net will still be a reduction“. By which Gary thinks Ramanathan is saying something like:

..measurements from a specific location at a later date when CO2 has increased will always lead to a reduction in OLR..

-my paraphrase.

But no, he has totally misunderstood what the author is saying. Ramanathan is doing a quick drive through of the basics and explaining how the greenhouse effect works.

Lower temperatures in the atmosphere mean that the radiation to space from this lower temperature atmosphere is lower than the radiation from the surface. (This is the “net trapping”). Therefore – the “greenhouse” effect. There is no conclusion here that “at all times in all situations increases in “greenhouse” gases will lead to a reduction in OLR in these bands“. The conclusion is just that “greenhouse” gases mean that the surface is warmer than it would be without these gases

And the first claim, Ramanathan said:

By deduction.. an increase in a greenhouse gas such as CO2 will lead to a further reduction in OLR. If the solar absorption remains the same, there will be a net heating of the planet.

Gary said:

Notice there is no clarifying statement about having to use model simulated graphs to ‘correct’ for surface temperatures and water vapor before seeing that OLR reduction.

That’s because the basics of the theory are the solid foundation and don’t need to be restated as qualifiers to every statement. Ramanathan helped write the theory! For people who think that this stuff is just some added extra, read his 1978 paper and see all the maths and the explanations. This is the theory.

In the earlier part of his earlier statement he said “Since the emission increases with temperature” but didn’t qualify it with “emission increases in proportion to the 4th power of temperature“.

Is Ramanathan losing confidence in the Stefan-Boltzmann formula? Or Planck? Are these rocks crumbling?

It’s only because Gary has decided that these points are somehow rocky that he would reach these conclusions. (And I could pick 10’s of other statements in the paper which, without qualifiers, could be taken to be the beginning of the end of a specific theory).

As a general point – when we look at the hypothetical global annual average after “new equilibrium” from increased CO2 is reached – if this new equilibrium exists – the theory (1st law of thermodynamics) predicts that the “new” OLR will match the “old” OLR (global annual average). And in that case the OLR in “greenhouse” gas bands will be reduced a little, while the OLR outside of those bands will be increased a little.

But when we look at one local situation we need the theory, also known as “the model”, also known as equations, to tell us what exactly the result will be.

Ramanathan hasn’t cast any doubt on it. He believes it. His papers from the 1970s to today work it all out. He just doesn’t write qualifiers to each statement as if every line will be read by people who don’t understand the theory..

### Gary’s Maths

In Gary’s comment he reproduced his back of envelope calculations of how much surface temperature should have changed over this 27 year period.

He takes the charitable approach of considering a net reduction in OLR from one of the three papers he originally reviewed – if I understood this step correctly. The figure he takes to work with is a 1K reduction. And then tries to work out how much this 1K reduction in OLR in the CO2 band would have on surface temperatures.

Like all good science this starts on napkins and the back of envelopes, because everyone studying a problem first has to attempt to quantify it using available data and available formulae. Then when the first results are worked out and it seems like something new is discovered – or something old overturned – then the scientist, patent clerk, writer now has to turn to more serious methods.

In Gary’s preliminary results he shows that a reduction in OLR due to CO2 might have contributed something like 0.3°C to surface temperature change over 30 years or so – where the GISS temperature increase for the period is something like 0.7°C. The essence of the calculation was comparing the Planck function (see the first and second graph in this post) of two temperatures 1K apart, then considering how much is in the CO2 band and so calculating the approximate change in W/m2. Then by applying a “climate sensitivity” number from realclimate.org, converting that into a temperature change.

Radiative physics has the potential to confuse everyone. Perhaps if we consider the “equilibrium case”, one problem with Gary’s calculation above will become clearer.

What’s the equilibrium case? In fact, it’s one generalized result of the real theory. And because it’s easier to understand than dI = -Inσdz + Bnσdz = (I – B)dχ people start to think the generalized result under equilibrium is the theory..

Under equilibrium, energy out = energy in. This is for the whole climate system. So we calculate the incoming solar radiation that is absorbed, averaged across the complete surface area of the earth = 239 W/m2.

So if the planet is not heating up or cooling down, energy out (OLR) must also = 239 W/m2.

So we consider the golden age of equilibrium in 1800 or thereabouts. We’ll assume the above numbers are true for that case. Then lots of CO2 (and other stuff) was added. Let’s suppose CO2 has reached the new current CO2 level of 380ppm – and stays constant from now on. The downward radiative forcing as calculated at “top of atmosphere” from the increase in CO2 is 1.7 W/m2. And nothing else happens in the climate (“all other things being equal” as we say).

Eventually we will reach the new equilibrium. Doesn’t matter how long it takes, but let’s pretend it’s 2020. Before equilibrium the planet will be heating up, which means OLR < 239 W/m2 (because more energy must come into the planet than leave the planet for it to warm up). At equilibrium, in 2020, OLR = 239 W/m2 – once again. (Of course, at wavelengths around 15μm the energy will be lower than in 1800 and other wavelengths the energy will be higher).

At this new equilibrium point we still have a “radiative forcing” of 1.7W/m2, which is why the surface temperature is higher, but no change in OLR when measured at 1800 and again at 2020.

We’ll assume, like Gary, the realclimate.org climate sensitivity – how do we calculate the new equilibrium temperature?

The change in OLR is 0.0 W/m2. Therefore, change in temperature = 0’C. Ha, we’ve proved realclimate wrong. Climate sensitivity cannot exist.

Or, it was wrongly applied.

As trace gases like CO2 increase in concentration they absorb energy. The atmosphere warms up and re-radiates the energy in all direction. Simplifying, we say it re-radiates both up and down. The extra downward radiation is what is used to work out changes in surface temperature. Not the immediate or eventual change in OLR.

The extra downward part is usually called “radiative forcing” and comes with a number of definitions you can see in Part Seven of the CO2 series (along with my mistaken attempt to do a “back of envelope” calculation of surface temperature changes without feedback).

How do we work out the change in surface temperature?

In Gary’s case, what he will need to know is the change in downward longwave radiation. Not upwards.

### Conclusion

The theory of radiative transfer in the atmosphere, at its heart, is a relatively simple one – but in application is a very challenging one computationally speaking. Therefore, it’s hard to grasp it in its details intuitively.

The theory isn’t the generalized idea of what will happen when moving from one equilibrium state to another equilibrium state with more “greenhouse” gases. That is a consequence of the theory under specific (and idealized) circumstances.

But because everyone likes shorthand, to many people this has become “the theory”. So when someone applies the maths to a specific situation it is “suspicious”. Maths becomes equated with “models” which to many people means “GCMs” which means “make-belief”. I think that if Gary had read Climate Modeling through Radiative-Convective Models by the Great Ramanthan, he might have a different opinion about the later paper and whether Ramanathan is “bailing out” on the extremely solid theory of “greenhouse” gases.

Anyone who has read a book on atmospheric physics would know that Gary’s claim is – no nice way to say it – “unsupported”. Yes – cruel, harsh, wounding words – but it had to be said.

However, most of the readers here and most on American Thinker haven’t read an undergraduate book on the topic. So it makes it worth trying to explain in some detail.

It’s also great to see people trying to validate or falsify theories with a little maths. Working out some numbers is an essential step in proving or disproving our own theories and those of others. In the example Gary provided he didn’t apply the correct calculation. (The subsequent pages of Ramanathan’s 1998 paper also run through these basics).

For those convinced that the idea that more CO2 will warm the surface of the planet is some crazy theory – these words are in vain.

But for the many more people who want to understand climate science, hopefully this article provides some perspective. The claims in American Thinker might at first sight seem to be a major problem to an important theory. But they aren’t.

Note – I haven’t yet opened the Philipona paper, but will do so in coming weeks and probably add another article about it. I didn’t want to leave Gary’s comments unanswered, and this post is already long enough..

Note on a Few Technical Matters

A few clarifications are in order, for people who like to get their teeth into the technical details.

Strictly speaking, at the very top of atmosphere there is no downward longwave forcing at all. That’s because there’s no atmosphere to radiate.

The IPCC definition of “radiative forcing” at “top of atmosphere” is a handy comparison tool of extra downward radiation before feedbacks and before equilibrium of the surface or troposphere is reached. In reality the increase in downward radiation doesn’t occur in just one location, extra downward longwave radiation occurs all throughout the troposphere and stratosphere.

In the example above, from 2010 to 2020 as surface and troposphere temperatures increased, radiative forcing would also increase slightly so it wouldn’t necessarily be constant at 1.7W/m2.

Climate sensitivity is calculated by GCMs to work out the resulting long term (“equilibrium”) temperature change, with climate feedbacks, from increased radiative forcing. No warranty express or implied as to their accuracy or usefulness, just explaining how to apply the climate sensitivity value correctly.

## Models, On – and Off – the Catwalk – Part Two

In Part One, we introduced some climate model basics, including uses of climate models (not all of which are about “projecting” the future).

And we took at a look at them in their best light – on the catwalk, as it were.

Well, really, we took a look at the ensemble of climate models. We didn’t actually see a climate model at all..

### Ensembles

The overall evaluation in Part One was the presentation of a “multi-model mean” or an ensemble. An ensemble can be the average of many models, or the average of one model run many times, or both combined.

We will return to more discussion about the curious nature of ensembles in a later post. Just as a starter, two observations from the IPCC.

IPCC AR4 in Chapter 8, Climate Models and their Evaluation, comments:

There is some evidence that the multi-model mean field is often in better agreement with observations than any of the fields simulated by the individual models (see Section 8.3.1.1.2), which supports continued reliance on a diversity of modelling approaches in projecting future climate change and provides some further interest in evaluating the multi-model mean results.

and a little later:

Why the multi-model mean field turns out to be closer to the observed than the fields in any of the individual models is the subject of ongoing research; a superficial explanation is that at each location and for each month, the model estimates tend to scatter around the correct value (more or less symmetrically), with no single model consistently closest to the observations. This, however, does not explain why the results should scatter in this way.

One interpretation of this would be:

We like ensembles because they give more accurate results, but we don’t really understand why..

A subject to come back to, now it’s time for a real model..

### Step Forward Climate Model “Cici” – CCSM3

CCSM3, “Cici”, is the model from NCAR (National Center for Atmospheric Research) in the USA. Out of all the GCMs discussed in the IPCC AR4, Cici has the “best curves” – the highest resolution grid. Well, she comes from the prestigious NCAR..

The model’s vital statistics – first the atmosphere:

• top of atmosphere = 2.2 hPa (=2.2mbar), this is pretty much the top of the stratosphere, around 50km
• grid size = 1.4° x 1.4° (T85)
• number of layers vertically = 26 (L26)

second, the oceans:

• grid size = 0.3°–1° x 1°
• number of vertical layers = 40 (L40)

The vital statistics give a quick indication of the level of resolution in the model. And there are also model components for sea ice and land. The model doesn’t need the infamous “flux adjustment” which is the balancing term for energy, momentum and water between the atmosphere and oceans required in most models to keep the two parts of the model working correctly.

The CCSM3 model is described in the paper: The Community Climate System Model Version 3 (CCSM3) by W.D. Collins et al, Journal of Climate (2006). The source code and information about the model is accessible at http://www.ccsm.ucar.edu/models/.

And for those who love equations, especially lots of vector calculus, take a look at the 220 page technical document on CAM3, the atmospheric component.

It will be surprising for many to learn that just about everything on this model is out in the open.

## CCSM3 Off the Catwalk – Hindcast Results

As with the multi-model means results in Part One we will take a look through a similar set of results for CCSM3.

### Annual temperature

CCSM3 Annual Land & Sea Temperature Actual (top) vs Model (bottom)

Cici looks pretty good.

Details – The HadISST (Rayner et al., 2003) climatology of SST for 1980-1999 and the CRU (Jones et al., 1999) climatology of surface air tempeature over land for 1961–1990 are shown here. The model results are for the same period of the CMIP3 20th Century simulations. In the presence of sea ice, the SST is assumed to be at the approximate freezing point of sea water (–1.8 °C).

However, it’s hard to tell looking at two sets of absolute values, so of course we turn to the difference between model and reality.

### Annual Temperature – Model Error

Model simulations of annual average temperature less observed values for Cici and for the “ensemble” or multi-model mean:

Annual Temperatures - Simulated minus observed for CCSM3 and the ensemble

In terms of absolute error around the globe, Cici and the ensemble are very close (using the Anglotzen statistical method).

We could note that even though the values are “close”, there are areas where Cici – and the ensemble – don’t do so well. In Cici’s case southern Greenland and the Labrador Sea, which might be very important for predicting the future of the thermohaline circulation. And both are particularly bad for Antarctica, a general problem for models.

To give an idea of the variation of models, here are all of the models reviewed by the IPCC in AR4 (2007):

Annual Temperature - Simulated minus observed - All models

The top right is Cici (red circle). It’s clear that Cici is a supermodel..

### Standard Deviation of Temperature

The standard deviation of temperature – “over the climatological monthly mean annual cycle ” – simulated less observed for Cici and the ensemble. We could describe it as how good is the model at working out how much temperature actually varies over the year in each location?

First, however, to make sense of the “error” of model less actual, we need to know what actual values look like:

Standard Deviation of Temperature over the climatological monthly mean annual cycle

As we would expect, the oceans show a lot less temperature variation than the land and around the tropics and sub-tropics the variation is close to zero.

Now let’s take a look at the model less actual, or “model error”:

Std Deviation of Temperature - Simulated minus observed for CCSM3 and the ensemble

We can see that Cici has some problems in modeling temperature variation especially under-estimating the actual variation around northern Russia and Canada and over-estimating the variation in the Middle East and Brazil. The ensemble appears to be in slightly better shape here.

Of course, these areas are where the largest temperature variation takes place.

### Diurnal Range of Land Temperature

As before, first the actual values:

Annual average of diurnal temperature range over land

And now the model less actual, or “model error”:

Diurnal temperature range over land - Actual less Model for CCSM3 and ensemble

We can see a lot of areas where the model error is quite large, usually corresponding to larger measured values. In the case of Greenland, for example, the annual average diurnal temperature range is over 20°C, while the model under-estimates this by more than 10°C. Given the legend the error might be as big as the actual value..

We can also see that on average Cici under-estimates the diurnal temperature range, and the ensemble is closer to neutral but still appears to under-estimate.

Here’s another comparison which demonstrates the problem of all the models vs observation:

Diurnal temperature range vs latitude - Observed compared with all models

The black line is the observed value. We can see that all of the models except for one are definitely under-estimating, and none of the models are particularly close to the observed values.

Now we can get to see more fundamental values.

This value is essential for calculating the basic radiation budget for the earth.

First the actual values as measured by ERBE (1985-1989):

And now the model error – model less actual:

Reflected Solar Radiation - Actual less Model for CCSM3 and ensemble

The ensemble is definitely better than Cici. Cici has some large errors, for example, North Africa, Pacific Ocean and the Western Indian Ocean where the model error seems to be up to half of the actual value.

If we look at the values averaged by latitude the results appear a little better:

Reflected Solar Radiation vs latitude - Observed compared with all models

But the deviations give us a better view:

Reflected Solar Radiation vs latitude - Model error for all models

Note Cici in the solid blue line. The ensemble is proving to be the pick of the bunch..

So the model’s ability to simulate reflected solar radiation is much better by latitude than by location. But most or all of the models have significant discrepancies even when averaged over each latitude.

The other side of the radiation budget, first the actual ERBE measurement (1985-1989):

And now the model error – model less actual:

OLR - Actual less Model for CCSM3 and ensemble

As with reflected SW radiation, the ensemble performs better than Cici. So while measured values are in the range of 200-300 W/m2, Cici has some areas where the (absolute) error is in excess of 30W/m2.

Looking at the OLR values averaged by latitude, the results appear a little better:

OLR vs latitude - Observed compared with all models

And the deviations, or model error:

OLR vs latitude - Model error for all models

### Rainfall

Measured from CMAP, 1980-1999:

Rainfall 1980-1999

Units are in cm of rainfall per year. And now the model error – model less actual:

Rainfall - Actual less Model for CCSM3 and ensemble

Once again the ensemble outshines Cici. There are some substantial errors in the areas where rainfall is high.

As with some of the previous model results, if we look at the model vs observed by latitude the picture is somewhat better:

Rainfall vs latitude - Observed vs all models

### Humidity

Lastly, we will take a look at specific humidity. First the “measured”, as recalculated by ERA-40:

Specific Humidity in g/kg vs Latitude and Altitude, from ERA40

Observed annual mean specific humidity in g/kg, averaged zonally, 1980-1999. Note that the vertical axis is pressure on the left in mbar and km in height on the right.

And now the model error – but this time in % = (model – actual)/actual x 100:﻿

Specific Humidity - % Error for CCSM3 and ensemble

Once again the ensemble appears to outperform Cici. And both, but especially Cici, have problems in the top half of the troposphere (around 500-200mbar) with 20-50% error in some regions in Cici’s case.

## Conclusion

This has been a quick survey of model results for different parameters across the globe, but averaged annually, compared with observations.

In Part One, we saw the ensemble in its best light. But when we take a look at a real model, the supermodel Cici, we can see that she has a lot of areas for improvement.

There’s lots more to investigate about models, all to come in future parts of this series.

As always, comments and questions are welcome, but remember the etiquette.

## The Earth’s Energy Budget – Part Three

In the previous article in this series, The Earth’s Energy Budget – Part Two we looked at outgoing longwave radiation (OLR) and energy imbalance. At the end of the article I promised that we would look at problems of measuring things and albedo but much time has passed, promises have been forgotten and the fascinating subject of how the earth really radiates energy needs to be looked at.

If you are new to the idea of incoming (absorbed) solar radiation being balanced by OLR, or wonder how the solar “constant” of 1367W/m2 can be balanced by the earth’s OLR of 239W/m2 then take a look at Part One and Part Two.

### Introduction

If you’ve read more in depth discussions about energy balance or CO2 “saturation” you might have read statements like:

More absorption by CO2 causes emission of radiation to move to higher, colder layers of the atmosphere

If these kind of comments confuse you, sound plain wrong, or cause you to furrow your brow because “it sounds like it’s probably right but what does it actually mean?” – well, hopefully some enlightenment can be found.

The sun’s core temperature is millions of degrees but we see a radiation from the sun that matches 5780K – its surface temperature:

Solar Radiation, top of atmosphere and at earth's surface, Taylor (2005)

In this figure there are two spectra: the top one is how the sun’s radiation looks before it reaches the top of the earth’s atmosphere – contrasted with the dotted line of a “blackbody” – or perfect radiator – at 5780K (5507°C for people new to Kelvin or absolute temperature).

The bottom one – of less interest for this article – is how the sun’s radiation looks at the earth’s surface after the atmosphere has absorbed at various wavelengths.

Why don’t we see a radiation spectrum from the sun that matches millions of degrees?

If we measure the upward longwave radiation from the earth’s surface at 15°C we see an effective “blackbody” radiator of 288K (15°C). But why don’t we see a radiation spectrum of 5000K – the temperature somewhere near the core?

The answer to both questions is that radiation from the hotter inner areas of these bodies gets completely absorbed by outer layers, which in turn heat up and radiate at lower temperatures. In the case of the sun, the radiation spectrum includes hotter areas below the surface that are not absorbed at some wavelengths, as well as the surface itself.

In the case of the earth it’s really the top skin layer that emits longwave radiation.

So when we measure the radiation from the earth with a surface temperature of 15°C (288K) we know we will see a longwave radiation that matches this 288K. This will be a total energy radiated of 390W/m2 with the peak wavelength of 10.1μm. The temperature below the surface is irrelevant.

(Well, it’s not really irrelevant. The hotter layers below warm up the layers above – through conduction and radiation).

This is what the radiation looks like:

Blackbody Radiation at 15'C or 288K

This assumes an emissivity of 1. The emissivity of the surface of the earth varies slightly but is close to 1, typically around 0.98. Watch out for a dull post on emissivity at some stage..

At the top of atmosphere, as many know, the OLR is around 239W/m2. For those confused by how it can be 390W/m2 at the surface and 239W/m2 at the top, the answer is due to absorption and re-radiation of longwave radiation by trace gases – the “greenhouse” effect. See the CO2 – An Insignificant Trace Gas? series, and especially Part Six – Visualization and CO2 Can’t Have that Effect Because.. if you don’t understand or agree with these well-proven ideas.

If the earth’s atmosphere was completely transparent to longwave radiation this spectrum would look exactly the same at the earth’s surface and at the top of atmosphere (TOA).

Here’s what it does look like with some typical blackbody radiation curves overlaid:

Outgoing longwave radiation at TOA, Taylor (2005)

(Note that the spectrum is shown in wavenumber in cm-1. For convenience I added wavelength in μm under the wavenumber axis. Wavelength in μm = 10,000/wavenumber).

For energy balance – if the earth is not warming up or cooling down – we would expect the earth to radiate out the same amount of energy that it absorbs from the sun. That amount is 239W/m2, which equates to an average temperature of 255K (-18°C).

As the text for this graphic shows, when the energy under the curve is integrated this is what it comes to! But as you can see the actual spectrum is not a “blackbody curve” for 255K. So let’s take a closer look.

### Everything Gets Through or Nothing Gets Through – a Few Thought Experiments

Imagine a world where the upwards longwave radiation from the earth’s surface didn’t get absorbed by any gases in the atmosphere.

Most people are familiar with that thought experiment – it’s a staple of the most basic radiation model in climate science. The radiation at the top of the atmosphere would look like this (the top graph):

This is the blackbody radiation at 255K (-18°C) with 100% “transmittance” through the atmosphere. The area under the curve, if we extend it out to infinity, is 239W/m2.

And of course, because the radiation hadn’t been absorbed or attenuated in any way, the temperature at the earth’s surface would also be 255K. Chilly.

Now let’s think about what would happen if the atmosphere allowed radiation only through the “atmospheric window” and everywhere else the transmittance was zero:

323K radiation through a perfect "atmospheric window", 8-14um

The bottom graph shows how the transmittance of the atmosphere varies with wavelength in this thought experiment.

The top graph in this case is the blackbody radiation from 323K (50°C) only allowed through between 8-14μm. The energy under the curve is 239W/m2. (Note the higher values on the vertical scale compared with the earlier graphs).

So if the atmosphere absorbed all of the surface radiation below 8μm and above 14μm the earth’s surface would heat up until it reached 50°C (323K). Why? Because if the temperature was only 15°C the amount of energy radiated out would only be 141W/m2. More energy coming in than going out = earth heats up. The surface temperature would keep heating up until eventually 239W/m2 made it out through the atmospheric window – which is 50°C.

### Closer to The Real World – Illustration of Radiation from Multiple Layers in the Atmosphere

Even in the atmospheric window some radiation is absorbed, i.e. the transmittance is not 1. But let’s assume for sake of argument it is 1. So energy in the 8-14μm band just passes straight through the atmosphere. It’s still a thought experiment.

Lots of gases absorb at lots of wavelengths – which makes thinking about it as a whole very difficult. So we’ll just assume that the rest of the atmosphere outside the atmospheric window all shares the same absorption characteristics – that is, every wavelength is identical in terms of absorption of radiation.

Now let’s try and consider what really happens in the atmosphere. Each “layer” of the atmosphere radiates out energy according to the temperature in that layer. For reference, here is the temperature (and pressure) at different heights:

Atmospheric Temperature & Pressure Profile, Bigg (2005)

The highlighted area at the bottom – the troposphere – is the area of interest. This is where most of the atmosphere (by molecules and mass) actually resides.

In our thought experiment radiation from the surface (outside the atmospheric window) gets completely absorbed by the atmosphere, or at least the amount that gets through is very small. Taken to the extreme we would get the result shown a few graphs earlier where the surface temperature rises up to 50’C.

But just because surface radiation doesn’t get out doesn’t mean that radiation from the atmosphere can’t get out.

Each layer of the atmosphere radiates according to its temperature. Even if the atmosphere’s transmittance is zero when considering the entire thickness of the atmosphere, there will be some layer where radiation starts to get through.

This is partly because there is less atmosphere to absorb the closer we get to the “top”. And also because as we get higher in the atmosphere it gets thinner. Less molecules to absorb radiation. Even if some gas is a fantastically good absorber of energy, there must be a point where radiation is hardly absorbed. For example, at the top of the stratosphere, about 50km, the pressure is around 1mbar – 1000x less than at the surface. At the top of the troposphere (the tropopause) the pressure is around 200mbar – 5x less than at the surface.

The challenge in thinking about the atmosphere radiating is that unlike the surface of the earth where all radiation is emitted from the very surface, instead radiation is emitted from lots of different layers:

• Higher up – less absorption, more radiation makes it through
• Lower down – more absorption, less radiation makes it through

But let’s still keep it simple and think about the surface temperature being our standard 15°C (288K) and the atmospheric window letting through everything between 8-14μm. This means 141W/m2 makes it out through this window.

If we have energy balance, the OLR = 239W/m2 in total = 141 (through the atmospheric window) + 98 (radiated from the atmosphere at some height, wavelengths outside 8-14μm).

What temperature equates to this layer in the atmosphere? Well, assuming no absorption above this radiating layer (not really the case), and only radiation outside 8-14μm, the temperature of the atmosphere would have to be 219K, or -54°C. Take a look back at the temperature profile above – this is pretty much the top of the troposphere, around 11km.

Remember that this isn’t exactly how radiation gets radiated out to space – it doesn’t come from one “skin layer”. We might consider that if the transmittance of the atmosphere is 1 at this height, then maybe at 10km the transmittance is 0.8 and at 9km the transmittance is 0.5, and at 8km the transmittance is 0.1..

So each layer is radiating energy, with higher layers being colder but more of their radiation getting through, and lower layers being warmer – so radiating a higher amount – but less of their radiation getting through.

For many people reading, this is a straightforward concept, why so long.. for others it might still seem tough to grasp..

So here is a sample radiation diagram with illustrative values only (and values a little different from above):

Radiation from different heights in the atmosphere, illustrative values only

What the diagram shows is the radiation outside the 8-14μm band. That’s because in our thought experiment the 8-14μm band doesn’t absorb any radiation (and therefore can’t radiate in this band either).

Take the top layer at 11km. If we calculate the blackbody radiation of 219K (-54°C) and exclude radiation in the 8-14μm band the radiation is 98W/m2. Then the grey block above with “0.6” is the atmosphere above with transmittance of 0.6, so the radiation actually getting through from this layer to the top of atmosphere is 59W/m2. Similarly for the two other layers (with different values).

In total, the energy leaving the top of atmosphere (outside of the atmospheric window) is 98W/m2. (It’s just a coincidence that this is the value of the top layer before any absorption). And inside the atmospheric window was the number we already calculated of 141W/m2, so the total OLR is 239W/m2.

Of course, we all know the real atmosphere is much more complex with lots of different absorption at different wavelengths. But hopefully this “intermediate” example help to explain how the atmosphere radiates out energy.

So finally, onto the real point..

### What Happens with More Absorbing Gases?

Remember how this long post started..

If you’ve read more in depth discussions about energy balance or CO2 “saturation” you might have read statements like:

More absorption by CO2 causes emission of radiation to move to higher, colder layers of the atmosphere

Now, maybe this kind of statement will make more sense.

In our model – our thought experiment – above, we had a uniform absorber of radiation outside the atmospheric window. Suppose we increase the amount of this absorber – the skies open and someone pours some more in and stirs it around. Let’s say the amount increases by 10%.

Well, take a look back at the last diagram. See the transmittance values for each layer in the atmosphere – 0.6 at 11km high, 0.25 at 10km high and 0.1 at 9km high.

Regardless of how realistic these actual numbers are, increasing the amount of absorbing gas by 10% will automatically mean that each of the transmittance numbers is reduced by 10%. And so less radiation makes it out to the TOA (top of atmosphere).

Effectively because lower layers are contributing less energy out through TOA the effective radiating height has moved up. It’s not because some directive has been passed down from a higher authority. And it’s not because one layer has stopped and another layer has taken over.

It’s just that lower layers contribute less, so the “average radiating height” is now higher and colder.

(Note: it might look at first sight that the average height is still the same even though the amount of radiation has reduced. This is not really the case, see the note at end).

In our particular example what would happen is that the OLR would reduce from 239W/m2 down to 141+98*0.9=229 W/m2. So the surface would warm up and this would warm up each layer of the atmosphere until eventually a new hotter steady state was reached.

### Conclusion

This has been a long post to try and create more of an understanding of how the earth actually radiates energy, and why more of any trace gas increases the “greenhouse” effect.

It does it because more “absorbing gases” reduce the amount of radiation that can make it out from lower layers in the atmosphere. These lower layers are hotter and radiate much more energy. Proportionately more energy will then be radiated from higher layers which are colder, and therefore these radiate less energy.

It’s a not a mystical force that raises the “effective radiating height” in the atmosphere. But the effective radiating height does increase.

Note

In the example above, the three layers together contributed 98W/m2 at TOA. That is an “effective temperature” of 219K – remembering that we are excluding radiation from the 8-14μm window. If we reduce the radiation from these three layers by 10%, we now have 89W/m2 which is about 212K – effectively radiating from a colder level in the atmosphere.

## The Imaginary Second Law of Thermodynamics

Many readers of this blog would like progress towards the solution of the great questions in climate science. Other readers have stopped by still pondering the basics.

Some of those pondering the basics might have read many of the exciting claims on the internet that the “greenhouse” effect can’t exist because it would violate the 2nd law of thermodynamics.

It’s not a claim that you find in any books on atmospheric physics by the way, it’s strictly an “internet phenomenon”.

Just a few basics in case this is the first post you have read from this site.

The inappropriately named “greenhouse” effect can be summed up in a few sentences:

Longwave radiation from the earth’s surface is absorbed by many trace gases, including water vapor and CO2. The absorption causes these gases to heat up and energy is radiated back out – both up and down. The upward radiation is effectively “no change”. The downward radiation adds to the energy received from the sun and heats up the surface of the earth more than if this downward radiation did not occur.

If there was no absorption of radiation by “greenhouse” gases the surface of the earth would be a lot colder. Here is a very simplified graphic to draw people’s attention to the fact that “something big” is going on:

Upward Longwave Radiation, Numbers from Kiehl & Trenberth (1997)

(TOA = top of atmosphere). If there was no absorption and re-radiation back down the two numbers would be the same. (Note that the downward radiation is not shown to crystallize the issue)

These numbers are global annual averages under a clear sky. Under a cloudy sky the numbers are different but similar – and still the radiation from the surface of the earth is a lot greater than that leaving through the top of atmosphere. For more on this take a look at CO2 – An Insignificant Trace Gas? – Part Six – Visualization and the followup CO2 Can’t Have That Effect Because.. as well as the start of the series on CO2.

Many people have said that the numbers are obviously wrong, I’m mixing up solar radiation and longwave radiation, it can’t happen, the temperature varies a lot from equator to poles so that’s why the radiation numbers are wrong..

As one person said on another blog, possibly commenting on one of these earlier posts:

I even saw one where the guy had 100 watts/m2 going into the atmosphere MORE than was coming out FOREVER.

Sharp-eyed readers might notice that I haven’t drawn in the downward radiation. Energy is balanced in the atmosphere because of the downward radiation from the atmosphere (not drawn). This is the “greenhouse” effect.

### Onto the Imaginary Second Law of Thermodynamics

How can a colder atmosphere add heat to a warmer surface?

Can a candle warm the sun?

There are many popular restatements of the imaginary 2nd law. These two should be a representative sample. And so follows the Q.E.D. claim that the “greenhouse” effect plainly contradicts the second law of thermodynamics.

What is the second law?

### The Real Second Law of Thermodynamics

My boring thermodynamics books and I have long since had a parting of the ways, so I looked it up on Wikipedia. Not a 100% reliable source, but the (real) second law is just as I remember it so I looked no further.

It’s possible that the imaginary second law has taken a strong hold because anyone who does look it up finds statements like dS/dt>=0, where S is entropy. Wow. Clever people. What’s entropy? How does this relate to candles? Candles can’t warm the sun, so I guess the second law has just proved the “greenhouse” effect wrong..

According to Wikipedia, Clausius expressed the second law (validly) like this:

Heat generally cannot flow spontaneously from a material at lower temperature to a material at higher temperature

Again, that seems right and it doesn’t have any entropy involved in the description. I never did like entropy. It never seemed real.

Perhaps this formulation has been the inspiration for the imaginary second law. As a not very precise definition many people might read this and think no energy at all can flow from a cold body to a hot body.

In fact, no net energy can flow from a cold body to a hot body.

In the case of the real “greenhouse” effect and the real 2nd law of thermodynamics, net energy is flowing from the earth to the atmosphere. But this doesn’t mean no energy can flow from the colder atmosphere to the warmer ground.

It simply means more energy flows from the warmer surface to the colder atmosphere than in the reverse direction.

Another likely reason the imaginary second law has become popular is most people are much more familiar with conduction of heat than radiation. Conduction of heat only appears to flow one way.

### A Thought Experiment

We’ll do a thought experiment to demonstrate why the imaginary second law of thermodynamics is wrong. It’s simpler, safer, cheaper AND more reliable than assembling equipment. After all, we are going to look at radiation and if we do an experiment we would need to ensure that no convection or conduction was taking place.

And the thought experiment will, I hope, be more powerful. Plus it will have the added benefit for those already convinced by the beguiling imaginary second law that they can say “you haven’t proven anything, it’s all in your head” and so the popular imaginary law can live on.

In our thought experiment we will consider the sun. It’s hot. It doesn’t conduct or convect any heat outside its immediate surface because space is a vacuum and heat can only travel by radiation through a vacuum.

So energy is radiated out from the sun equally in all directions. At a 1000km distance from the sun, we get our measuring instrument out and find that energy radiated is 10,000W/m2 (because I can’t be bothered to work out the actual number).

Now we fly in a cold large rock and park it at 1000km from the sun. Energy from the sun is absorbed on this cold rock and it heats up to some equilibrium value where it is also radiating out what it is receiving.

The temperature of this large once-cold rock is now a toasty 648K (375’C). All is well with both the real and imaginary formulations of the 2nd law, so far.

Now, from a galaxy far far away, we fly in a new star. Before we started moving it we checked the radiation 1000km away from the star and found that it was 11,000W/m2. We are careful in our relocation of this star that nothing changes in its inner generation of radiation. The new star is parked 1000km away from the once-cold rock and 1000km away from the sun.

It’s a love triangle. Due to the new star’s welcome appearance, the rock heats up further. It now receives 21,000W/m2. Its new equilibrium temperature is 780K. All is still well with both the real and imaginary formulations of the 2nd law.

But now a problem.. the new star is radiating out in all directions. Believers in the imaginary second law have no problem with the idea that the sun receives energy from the new star. After all the sun was a little colder.

But what about the sun? It is also radiating out in all directions. Or it was before the new star arrived.

Now that the new star is parked 1000km from the sun, squarely in the path of some portion of the sun’s radiation we have to ask ourselves what actually happens?

Believers in the real second law of thermodynamics are quite happy. No cognitive dissonance there. The energy from the sun which is incident on the new star’s surface actually increases the new star’s surface temperature compared with what it was before.

11,000W/m2 are flowing from the new star to the sun, and 10,000W/m2 are flowing from the sun to the new star. Some kind of new equilibrium might be reached, but for real second law believers there is no angst. The net flow of energy is from the hotter to the colder.

Believers in the imaginary second law, what happens?

One obvious suggestion is that the sun’s paltry 10,000W/m2 which was flowing through that exact spot now divert around the new star as if it had some kind of force field. Perhaps all the energy lines completely redistribute so that (depending on the diameter of this new star) about 10,015W/m2 flow in all directions except through the location of the new star.

Another obvious suggestion is that the sun “realizes” the new star is there and energy is flowing from the new star to it so just stops radiating in that exact direction. I put “realizes” in quotes of course because we all know the sun is not sentient. It’s just terminology. Some process that drives the imaginary second law will no doubt make this happen.

And the most likely suggestion of all is that this radiation from the sun, when it strikes the surface of the new star, just bounces off. Or is absorbed but doesn’t actually heat up the surface of the new star (unlike the inner radiation of this new star which does warm the surface from the inside).

### Conclusion

I can’t help thinking that all my explanations for the imaginary second law have their own problems. And so I welcome explanations from promoters of the theory for the physical processes that take place near the surface of the new star.

Perhaps the problem is in the thought experiment itself. After all, you can’t just fly a star in from another galaxy and park it close to the sun. Barking mad!

And so the Imaginary Second Law of Thermodynamics lives on!

Update – the imaginary law also covered (possibly created by) On the Miseducation of the Uninformed by Gerlich and Tscheuschner (2009)

Update – a worked example with the maths, Radiation Basics and the Imaginary Second Law of Thermodynamics

Update – and more explanation with reference to one advocates explanation of this imaginary law, Intelligent Materials and the Imaginary Second Law of Thermodynamics

## On Having a Laugh – by Gerlich and Tscheuschner (2009)

There’s a paper out which has created some excitement, On Falsification Of The Atmospheric CO2 Greenhouse Effects, by Gerlich & Tscheuschner (2009). It was published in International Journal of Modern Physics B. I don’t know what the B stands for.

Usually I would try and read a paper all the way through to understand it, then reread it.. but I got as far as page 55 out of 115 – even the seminal Climate Modeling through Radiative Convective Methods by Ramanathan & Coakley (1978) paper only had 25 pages.

Quite a few points have already jumped out at me that made me not want to read the whole thing:

First, a lot of time was spent showing that greenhouses and bodies surrounded by glass (or anything that stops air movement) retain heat not because of absorption and reradiation of longwave energy but because convection is reduced.

Why spend so long on it when everyone agrees. Sadly the “so-called greenhouse effect” became that because it passed into common language to describe this effect even though it’s not the right description.

I tried to think of a good analogy, something to bring it to life..

But didn’t mention greenhouses, because the greenhouse isn’t a good analogy..

This is a concern if it’s a serious paper, because attacking arguments that no one agrees with is the strawman fallacy, a refuge of people with no strong argument.

Here is a nice example, commenting on a paper by Lee, who says that the “greenhouse” term is a misnomer:

Lee continues his analysis with a calculation based on radiative balance equations, which are physically questionable.. Nevertheless, Lee’s paper is a milestone marking the day after which every serious scientist or science educator is no longer allowed to compare the greenhouse with the atmosphere, even in the classroom, which Lee explicitly refers to.

The authors of this paper don’t actually explain where Lee’s equations are questionable, instead draw attention to a day that should be marked down in history.. and use that to show that anyone mentioning “greenhouses” have got it wrong.

None of the papers that discuss the radiative-convective method actually argue from the greenhouse. So why are the authors of this paper spending so much time on it?

Second, attacking poor presentations with a mixture of correct (but really irrelevant) and incorrect arguments.

They cite, not a paper, but an Encyclopedia..

In the 1974 edition of Meyer’s Enzyklopadischem Lexikon one finds under “glass house eff ect”:

Name for the influence of the Earth’s atmosphere on the radiation and heat budget of the Earth, which compares to the e ffect of a glass house: Water vapor and carbon dioxide in the atmosphere let short wave solar radiation go through down to the Earth’s surface with a relative weak attenuation and, however, reflect the portion of long wave (heat) radiation which is emitted from the Earth’s surface

Disproof: Firstly, the main part of the solar radiation lies outside the visible light. Secondly, reflection is confused with emission.

Nice. They have brought this up a few times. Yes, technically we call infrared that part of the radiation that is longer wavelength than visible light. So anything >700nm is infrared. Any yet, in common terminology, often cited to a point of pain, we use “longwave” to mean that radiation over 4μm because 99% of it is radiated from the earth, and we use “shortwave” to mean that radiation under 4μm which is solar radiation.

So their first “disproof” isn’t a disproof. And their second one is simply picking a terminology mistake in an encyclopedia. Yes, the encyclopedia has mixed up the phenomenon.

Why are they citing from this source?

Third, another example of “destroying” the opponent’s argument..

They quote another source:

The infrared radiation that is emitted downwards from the atmosphere (the so-called back-radiation) raises the energy supply of the Earth’s surface.

And comment:

The assumption that if gases emit heat radiation, then they will emit it only downwards, is rather obscure.

It wasn’t what their source actually said. Their source didn’t say, or imply, that radiation was emitted only downward.

Fourth, and most importantly, the paper gives the appearance of discussing prior work by discussing a real mix of very old work and lots of more recent comments by people in their “introduction” to something quite different. That is they are citing from papers which are introducing another subject while not attempting to demonstrate any formal proof of the inappropriately named “greenhouse effect”. They don’t discuss the relevant modern work that attempts to prove the relevance and solution of the radiative transfer equations.

They do reference one key paper but never discuss it to point out any problems.

The paper in question is S. Manabe and R.F. Strickler, Thermal Equilibrium of the Atmosphere with Convective Adjustment, J. Atmosph. Sciences 21, 361-385 (1964)

It is referenced through this quote:

The influence of CO2 on the climate was also discussed thoroughly in a number of publications that appeared between 1909 and 1980, mainly in Germany. The most influential authors were Moller, who also wrote a textbook on meteorology, and Manabe (the citation). It seems, that the joint work of Moller and Manabe has had a signifi cant influence on the formulation of the modern atmospheric CO2 greenhouse conjectures and hypotheses, respectively.

The work that most recent papers on the solution to the radiative transfer equations discuss or cite is Ramanathan and Coakley (1978) – often along with a citation of M&S – and of course Ramanathan and Coakley cite and discuss Manabe and Strickler (1964). That is, anyone calculating the effect of CO2 and other trace gases on the surface temperatures.

Why not open up these two great papers and show the flaws? Ramanathan and Coakley are never even cited. Manabe and Strickler aren’t discussed.

R&C is 25 pages long and works through a lot of thermodynamics in their paper. If Gerlich & Tscheuschner want to get a result, show their flaws. It should be a breeze for them..

This doesn’t instill any confidence in the paper. I starting writing this post a few weeks ago and at the time wrote:

One day I may find the energy to read and reread all 115 pages and do them justice. Perhaps there is some revelation inside. More likely, they are having a laugh. Otherwise why is half the paper nothing to do with disproving the theory that modern atmospheric physicists believe?

I’m sure they would say otherwise.. And I’m certain we would get on great over a few drinks. If we drank enough I’m sure they would admit they did it for a bet..

### Non-Conclusion

If Gerlich & Tscheuschner want to be taken seriously maybe they can write a paper which is 20-30 pages long – it should be enough – and they can ignore greenhouses and encyclopedia references and what people say in introductions to less relevant works.

Their paper could reference and discuss recent work which from first principles demonstrate and solve the radiative transfer equations. And they should show the flaw in these papers. Use Ramanathan and Coakley (1978) – everyone else references it.

On that paper: Climate Modeling through Radiative Convective Methods – R&C are into the maths by page 2 and don’t mention greenhouses. I would recommend this excellent paper (you should be able to find it online without paying) to anyone who wants to learn more about the approach to solving this difficult but well-understood problem. Even if you don’t want to follow their maths there is lots to learn.

Gerlich & Tscheuschner waste 50 pages with irrelevance and poorly directed criticism.. if they have produced a great insight it will be lost on many.

In New Theory Proves AGW Wrong! I commented that many ideas come along which are widely celebrated.

Some “disprove” the “greenhouse effect” or modify it to the extent that if their ideas are correct our ideas about the (inappropriately named) greenhouse effect are quite wrong.

Some disprove AGW (anthropogenic global warming). There is a world of difference between the two.

This paper falls into the first category. I also commented that the papers in the first category usually disprove each other as well, so it’s not “one more nail in the greenhouse effect” – it’s “one more nail in the last theory” and the theories that will inevitably follow.

Interestingly (for me), since I wrote that article: New Theory Proves AGW Wrong! someone produced a list of a few papers that I should “disprove”. One was this paper by Gerlich and Tschueschner, another was by Miskolczi. Yet they disprove each other and both disprove what this person promoted as their own theory.

This doesn’t prove anyone wrong – just they can’t all be right. One or zero..

And I’ll be the first to admit I haven’t proven Gerlich and Tschueschner wrong in their central theory. I have pointed out a few “areas for improvement” in their paper but these are all distractions from the main event. More interesting stuff to do.

Update – new post: On the Miseducation of the Uninformed by Gerlich and Tscheuschner (2009)