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A long and interesting discussion followed Venusian Mysteries. One commenter posed an excellent thought experiment:

Consider Venus with its existing atmosphere, and put a totally opaque enclosure (to incoming Solar radiation) around the entire planet at the average location of present outgoing long wave radiation. Use a surface with the same albedo as present Venus for the enclosure.

What would happen to the planetary surface temperature over a reasonably long time?

For this case, NO Solar incoming radiation reaches the surface. I contend that the surface temperature will be about the same as present.

Now assume the gas temperature and distribution are initially different from present levels, but no gases are condensed other than those that form the present clouds. I contend the temperature will go to about the present distribution and level. The only reason for this not to not match exactly the same as the actual atmosphere would be due to the fact that for the atmosphere, outgoing radiation actually leaves from a finite gas thickness, but the present version is a surface.

With further clarification:

Assume the surface has a black body emissivity for the long wave outgoing radiation. Also assume it is a thin but good conducting material.

And also answered that the opaque enclosure radiates in both directions (both outgoing to space and to the surface of the planet).

The First Simple Model

Here’s a very simple radiative balance below. The “opaque enclosure” is E, and the surface is S. This has one layer of opaque atmosphere,1, to get us started:

The gaps in the diagram are simply to enable us to see the radiation values from each layer more easily – they don’t represent any kind of physical discontinuity.

I started with a many layer model of the atmosphere – as described a little in Venusian Mysteries.

As a result of the solution to the equations, it made sense to explain a one layer model of the atmosphere first. I started by assuming that the initial conditions were that the enclosure and surface were initially very cold to see what happens.

Because E is a “thin but good conducting layer” we assume that E is “isothermal” – all at the same temperature. And because it is thin we assume that it heats up quickly when irradiated by solar energy – i.e., its heat capacity is low so it doesn’t take long to reach equilibrium.

Because gases have very low conductivity, and because radiation from the inside surface of the “opaque layer” is taking place, we assume that radiation to the surface is “much greater” than conductivity.

In this simple (unrealistic) one layer model, we also assume that the atmosphere is isothermal (all at one temperature). This is just to get us started. We can add a many layer model later, where each layer is isothermal, but each layer is at a different temperature from the ones above and below.

A Little Maths

Reviewing the diagram above, assuming that radiation is the only heat transfer mechanism, and assuming that the solar radiation is equally spread (note 1 at end):

TSI + R1 = 2RE [1]

2R1 = RS + RE [2]

RS = R1 [3]

So:

[3] -> [2]   2RS = RS + RE, or RS = RE [4]

[4], [3] -> [1]   TSI + RS = 2RS, or TSI = RS

And so, in equilibrium (after every layer has heated up to steady state):

RS = R1 = RE = TSI

That is, each layer radiates the same as every other, and at the same value as the solar irradiance of 158 W/m2 (absorbed solar radiation).

Which means that the enclosure layer will reach an equilibrium temperature of 229K – and this will also be the equilibrium planetary surface temperature.

If these are the equilibrium temperatures what will drive conduction or convection of heat? Nothing. With the surface, the atmosphere and the “enclosure layer” of our thought experiment, all at the same temperature there will be no convection or conduction.

The Many Layer Model

The example above can be extended to many layers of opaque atmosphere. I checked out a 3-atmospheric layer model and the same results are obtained. (It’s tedious writing down the 5 equations and showing the substitutions to solve, especially as wordpress doesn’t do subscripts easily).

But the more realistic many-layer models solve exactly the same way. So with an outer atmospheric layer absorbing the solar radiation and then heating up and radiating in to the surface (and out to space), we find that the surface is no hotter than the outer atmospheric layer.

Compare this with the many layer model in the original article (under How Can the Surface Get so Hot? An Over-Simplified Climate Model), where, because the surface was heated by solar irradiance, the surface could become much hotter due to “backradiation” from the many layers above.

Then, in that model, as a result of the high surface temperatures, convection was initiated which moderated the high temperatures.

In this model, radiation can’t create those conditions – at least from a cold starting condition.

[Note added, 25th June – This model is aimed at demonstrating that radiative effects through an opaque atmosphere are totally different when the solar radiation is received at the outer layer of the atmosphere compared with at the surface. The “isothermal” model of the atmosphere (=the atmosphere all at the same temperature) is just for the purposes of constructing this radiation model – and as Leonard Weinstein points out, his thought experiment explicitly stated that the atmospheric temperature varies. In a “many layer” model with low conductivity (as found in gases) the radiation model would still be valid, even though the temperature varies from night to day and at different latitudes. Therefore, another mechanism of significant heat transfer is required to get the surface temperature of “thought experiment Venus” (TEV) to the temperature of actual Venus.

So in normal Venus we have a mechanism – radiation – for driving the temperature so high. But in TEV we need another mechanism.]

What about the Real World Effects?

In practice, one half of the atmosphere is heated during the day while the other half cools, and vice-versa for the night. This doesn’t affect conduction which has a tiny effect.

Does this create a stronger heating through to the surface and initiate some convective activities? How about if we started with a hot surface (from volcanic activity), would we reach a different equilibrium effect?

In both of these cases, there is no explanation for why any convective lapse rate would be maintained – unless a high source of internal heat from something like volcanic activity was maintained.

If we started with a hot initial condition (but no ongoing source of heat) instead of a cold initial condition, convection would simply move heat up to the top of the atmosphere until the same steady state condition was reached – where each layer was at the same temperature.

Convection is the bulk movement of heat as gases or liquids carry heat from one location to another. But something needs to drive convection. In the case of the earth’s atmosphere it is the relatively high surface temperature (from radiation) heating gases which expand and so are less dense. Gases that are less dense rise – and so heat is moved more effectively from the surface than can be achieved by radiation.

When heating the atmosphere from the top – with the vacuum of space above – there is no explanation for high temperatures in layers below.

In the case of the real Venus we at least saw what a totally opaque atmosphere could achieve. In the case of this thought experiment we see a totally different result.

Perhaps someone can produce a more comprehensive model which shows how the surface could radiate at 16,000 W/m2 in this thought experiment. I doubt that it can be done.

Note 1: If we assume that the solar radiation is equally spread across all surface elements, we get the result in the 1-layer or many-layer model. Strictly speaking this is not the case – as the solar radiation only heats one side of the planet at any one time, and that somewhat unequally. Is this a good approximation? Yes, if the heat capacity of the atmosphere is sufficiently high.

If the heat capacity is lower we simply get a relatively hotter surface temperature during “the day” and a relatively colder surface temperature during “the night”. No mechanism for Venusian surface temperatures.

UpdateNew article – Convection, Venus, Thought Experiments and Tall Rooms Full of Gas – A Discussion

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The surface of Venus is around 730K (457°C) – why is it so hot? Although there is still much to learn about Venus the basics have some simple explanations.

Energy Absorbed from the Sun

While earth is 150M km from the sun, Venus is only 108M km away, a ratio of 0.72.

The “solar constant” (as it has been historically called) at the earth is 1367 W/m², and, as energy intensity is proportional to the square of the distance away, or “r²”, the solar constant at Venus is 1367/(0.72²) = 2,636 W/m² – Venus is closer, so it receives more solar energy per m².

The earth has an average albedo of about 0.3, meaning that 30% of the solar radiation is reflected. This is by clouds, by aerosols in the atmosphere, and by the surface of the earth. (Watch out for “The Earth’s Energy Budget – Part Four – Albedo”). If Venus had the same albedo as the earth, the energy absorbed per m² of surface area would be, E = 2,636 * (1-0.3) / 4 = 461 W/m². [corrected – thanks to Bill Stoltzfus for pointing out my mistake]

For an explanation of why the value is divided by 4, see The Earth’s Energy Budget – Part One

This value equates to an “effective radiating temperature” of 300K (27°C). This is nothing like the surface of Venus. [corrected as well – thanks to Bill Stoltzfus for pointing out my mistake]

In any case, it turns out that Venus has a much higher albedo than the earth, with an albedo of 0.76 – meaning that 76% of the solar energy is reflected.

Redoing the calculation, E = 2,636 * (1-0.76) / 4 = 158 W/m² – which equates to an “effective radiating temperature” of 230K (-43°C). The same calculation for the earth gives 255K (-18°C) – see CO2 – An Insignificant Trace Gas? – Part One.

So in terms of a simple energy balance with the sun, Venus should be colder than the earth.

In the case of the earth, as laid out in the CO2 series, the reason the surface of the earth is so much warmer than predicted from simple energy balance is because various trace gases, including water vapor and CO2, absorb the upward radiation from the earth’s surface and reradiate it in all directions. As some of this is downward, the surface of the earth receives more energy than it would without these gases and so it is hotter. See CO2 – An Insignificant Trace Gas? Part Six – Visualization for some more insight into this.

So is Venus so much warmer at its surface because of the inappropriately-named “greenhouse” effect? Or is it for other reasons?

The Venusian Atmosphere

The atmosphere of Venus is quite unwelcoming for us earth-dwellers. The atmosphere is mostly CO2 (97%), with the balance made up mostly of nitrogen (N2), and trace amounts of water vapor and many other gases in minute quantities.

The mass of the Venusian atmosphere is around 100 times that of the earth, and consequently the pressure at the surface of Venus is much higher – at 92bar compared with 1bar for the earth.

Now some people say that the reason for the high temperature at the surface of Venus is because of the high atmospheric pressure and the depth of the atmosphere. For example, Steve Goddard on Wattsupwiththat and echoed by Lubos Motl. This explanation isn’t one that you can find in atmospheric physics text books.

A Quick Review of the Earth’s Surface

This is just to explain a few basics for some perspective.

From Trenberth and Kiehl (1997)

From Trenberth and Kiehl (1997)

There’s much of interest in this diagram from Earth’s Annual Global Mean Energy Budget by Trenberth and Kiehl (1997) but we’ll focus on a few key elements for the purposes of this article.

The surface of the earth receives an average of about 170 W/m² from solar energy (with an additional 70W/m² of solar radiation absorbed by the atmosphere). The earth’s surface also receives an average of 324 W/m² of radiation from the atmosphere. So in total the earth’s surface receives about 490 W/m² (annual global average).

Now the average radiation from the surface of the earth is 396 W/m² (or 390 W/m² in the diagram above, which is close enough for our purposes). Convection and conduction remove the balance of around 100W/m². If you take a look at Tropospheric Basics you can see more about the temperature profile in the troposphere (lower atmosphere) and why convection is a more effective re-distributor of heat within the troposphere.

The principal point is that the warming of the air from the surface radiation, conduction and convection causes the air to expand. Air that expands is less dense, and so this air rises, moving heat by convection.

The temperature profile, or lapse rate, from convection can be easily calculated, both for dry air and moist air. Dry air is just under 10°C/km, while moist air depends on the amount of water vapor, but can be as low as 4°C/km. (And the environmental lapse rate, or what we find in practice, is around 6.5°C/km).

So in the case of the earth’s surface, it would be radiating out 490W/m², but for the fact that conduction and convection remove some of this energy from the surface, and then convection redistributes this energy up into the atmosphere.

The Surface of Venus

Energy radiated from a surface is proportional to the 4th power of absolute temperature. This is known as the Stefan-Boltzmann law but visualizing the 4th power of something isn’t that easy. However, calculators are readily available and so if you punch the numbers in you will see that for a surface of T=730K with an emissivity close to a blackbody:

E = 16,100 W/m²   – compare this with the surface of earth (288K, 15°C) of around 390 W/m²

This is over 40x the energy radiated from the surface of the earth – for a temperature only 2.5x greater. That’s the real world, very non-linear.. (And note that if the emissivity is not equal to 1, the energy radiated is simply the value above multiplied by the emissivity).

So if we think about the top of atmosphere of Venus, it is radiating round about 158 W/m². This balances the absorbed solar radiation. And yet the surface is radiating 16,100 W/m² – does the high pressure of the Venusian atmosphere explain it?

No

Think about it like this. For the surface of Venus to be radiating at 16,100 W/m² it has to be receiving this energy from somewhere. It receives a maximum of 158 W/m² from the sun (if all of the solar energy absorbed is absorbed in the surface and nothing in the atmosphere).

The explanation from others about a temperature gradient between the surface and the tropopause (top of the tropopause or lower atmosphere) only explains anything when the surface heats the atmosphere from below. In that case the atmosphere heats up, expands and rises – moving energy via bulk movements of air.

Can the atmosphere create heat from pressure and transmit this heat to the surface?

In the case of the earth’s surface, the extra radiation to the earth’s surface (caused by the “greenhouse” effect) heats the atmosphere from beneath and causes convection – with a lapse rate (or temperature profile) of between 4 – 10 °C/km. And convection moves some of this heat from the surface up into the atmosphere. In the case of Venus the argument that relegates the role of the “greenhouse” effect and promotes the role of atmospheric pressure doesn’t have a heat transfer mechanism.

Picture the starting condition where the surface is very cold. What heats it up?

There are three ways of moving heat – radiation, convection and conduction. Conduction in gases is extremely low and anyway the top of the atmosphere is around 230K – if the surface starts off colder what causes heat to flow to the surface to create such a huge emission of radiation?

Convection needs to work by warming a gas from below. Where is this mechanism if the surface is not already heated by the “greenhouse” effect?

And radiation has been ruled out (as the main mechanism) in these arguments from Steve Goddard and others.

How Can the Surface Get so Hot? An Over-Simplified Climate Model

Let’s take a look at the ignored radiation and the super “greenhouse” effect.

How can a surface get so hot from “back-radiation”? Isn’t that just as crazy an idea?

We will take a simple idea – as all models are at their start, just to demonstrate a point. There’s a little bit of maths, unfortunately, but possibly (if you haven’t seen this concept before), the concept might actually seem harder to grasp. Here’s a very simple (and not very realistic) model of a planetary surface and atmosphere (idea from Radiation and Climate from Vardavas and Taylor (2007)):

Simple climate model - atmosphere perfectly transparent to solar radiation, and totally opaque in the infra-red

Simple climate model - atmosphere perfectly transparent to solar radiation, and totally opaque in the infra-red

The surface receives radiation from the sun, S. In the case of Venus this value would be (averaged across the surface), S = 158 W/m².

Now the surface is at Ts and radiates to the atmosphere, which heats it up. The atmosphere is perfectly transparent to solar radiation, but totally opaque in the infra-red and all at one temperature, Ta. Therefore, the atmosphere radiates σTa4 upwards and σTa4 downwards.

Note that “totally opaque” means that no surface radiation makes it through this layer of the atmosphere. In this scenario we can calculate the surface radiation. If you are new to this kind of model, it is easiest to follow the small amount of maths against the graphic. First, using the simple energy balance at top of atmosphere, the outgoing radiation at the top of atmosphere equals the absorbed solar radiation averaged over the surface of the earth:

σTa4 = S         [equation 1] – this is the Stefan-Boltzmann law, where σ = 5.67 x 10-8

Second, the surface radiation balances the energy received at the surface – which is from the sun and the atmosphere:

S + σTa4 = σTs4 [equation 2]

Therefore, substituting [1] into [2], we get:

σTa4 + σTa4 = σTs4

2σTa4 = σTs4, or 2S = σTs4

and solving we find, Ts = (2S/σ)1/4

In the case of S = 158 W/m², Ts = 273K

Now effective temperature at the top of atmosphere is 230K, so an opaque atmosphere has increased the surface temperature significantly – but not to 730K. (Barton Paul Levenson has a model like this, commented on in CO2 – An Insignificant Trace Gas? Part Eight – Saturation)

Now with a very optically thick atmosphere, we simply add more and more layers to our model. The equations get slightly harder to solve, but each time we add a new totally opaque layer the temperature rises yet more.

For example, with 3 totally opaque layers the solution to a similar set of equations (with 4 equations and 4 unknowns) is:

Ts = (4S/σ)1/4, or Ts = 328K

It should be easy to see how the surface temperature gets extremely hot from radiation with many layers of opaque atmosphere (yet transparent to solar radiation).

So the Surface Temperature is Infinite, you Dummy!!

Well, if we can keep adding layers, and each one just increases the “back radiation” anyone can see that this can go on forever and the temperature will be infinite!

Obviously the model is wrong..

Not quite (well, if we could keep doing this, the model would be wrong). In the model above we have one totally opaque layer of atmosphere. But once we add multiple layers we are effectively dividing up the real atmosphere and saying that each layer is totally opaque. As we keep sub-dividing the atmosphere into more and more layers eventually they start to get optically thin and the radiation from the layer below will not be completely absorbed.

Radiation from CO2

All the above model does is demonstrate how the presence of significant radiatively absorbing gases can significantly increase the surface temperature. A 97% CO2 atmosphere is different from the model above for two reasons:

  • CO2 doesn’t absorb at all terrestrial wavelengths so it isn’t a perfect absorber
  • convection will moderate the surface temperature increase – once induced by radiation – as with the earth’s surface

So to calculate the effect of the CO2 atmosphere we have to solve the radiative transfer equations, which you can see in CO2 – An Insignificant Trace Gas? Part Three and Part Five (and the whole series).

These are fundamental equations of absorption and emission, but aren’t really solvable on a pocket calculator – despite so many people appearing to do just that in so many blogs.  Note as well that CO2 spectral lines broaden with pressure so that CO2 (and water vapor) become a much more effective absorber in the lower Venusian atmosphere than the earth’s.

And we have to consider that once we have very high temperatures at the surface, convection will begin to move heat more effectively. This essentially moderates the effect of radiation.

But for those who believe that high Venusian atmospheric pressure and the ideal gas laws cause the high 730K surface temperature – they have to explain how the heat is transferred to the surface so that it can radiate at 16,100 W/m².

Real Solutions

One early approach to using real atmospheric physics on this problem was by James Pollack (reference below) in 1969 who showed that that plausible amounts of water vapor and the very high levels of CO2 could explain the high temperatures – using the radiative transfer equations and a convective model.

Bullock and Grinspoon (reference below) did this more recent calculation of the temperature profile in the Venusian atmosphere:

And they note a few possible reasons for the divergence above 70km. The model produces this spectrum of outgoing radiation:

The Planck function for an “effective radiating temperature” of 232K is shown. Note that the much higher levels of flux (in comparison to the 232K curve) demonstrate that at lower wavelengths (higher wavenumbers) the atmosphere is less opaque. This tends to limit further temperature rises, as the presence of any “window” regions allows a higher surface temperature to radiate out efficiently to the atmosphere.

A Mental Model

One mental model for people new to the inappropriately-named “greenhouse” effect is to think about the sun as an internal heat source, and CO2 as some kind of insulator.

Picture an ambient temperature of 20°C and a surface which has a constant internal heat source. As you add more and more insulation around this surface the temperature will keep rising – as heat is less able to flow away from the surface. For a given insulation there will be an equilibrium temperature reached that we can calculate, and it will be a function of the properties of the insulation.

Even though the temperature might reach 100°C or 200°C doesn’t mean that energy is “created” in this model – and this is probably clear to everyone.

Whether or not mental models “work” doesn’t change the realities of physics, but of course everyone wants to understand a subject conceptually.

Conclusion

Venus follows the same physical laws as the earth, so explaining the high surface temperature should be possible, even though many details of the atmosphere of Venus are hidden from us.

Some people who have attempted to explain the high Venusian surface temperature have used the ideas about the relationships between pressure and temperature in ideal gases without the strong “greenhouse” effect of a 97% CO2 atmosphere.

However, these ideas seem to lack a heat transfer mechanism whereby the surface of Venus can radiate at 16,100 W/m². This is the missing element in ideas which eliminate or relegate the role of CO2. In contrast, high surface temperatures in very strongly absorbing atmospheres can be explained using the radiative effects. A simple model can demonstrate very high temperatures, but a thorough calculation does require solution of the radiative transfer equations.

Update – New articles – Convection, Venus, Thought Experiments and Tall Rooms Full of Gas – A Discussion

Venusian Mysteries – Part Two

Reference

A Nongray CO2-H2O Greenhouse Model of Venus, James Pollack, Icarus (1969)

The Recent Evolution of Climate on Venus, Mark Bullock and David Grinspoon, Icarus (2001)

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On Lunar Madness and Physics Basics, one commenter asked a very good question in response to a badly phrased answer from me.

He originally asked:

You agree that if earth had 100% nitrogen atmosphere (a non greenhouse gas), the “average” temperature of earth would be different (I’m not entirely sure it wouldn’t be lower) from the 255 K blackbody radiation would suggest.

I got the meaning wrong and said “right, it would be 255K” and wasn’t very specific with what I meant, which was a mistake as the article in question had just explained everything wrong with averages..

He responded with an interesting example of a fictional Latvia, where Latvia got all the solar energy (somehow) and the rest of the world none, and showed that the average temperature of the earth was 0.5K or almost -273°C (and Latvia was quite steamy).

And after I had written a comment as long as a post I thought it was probably a subject that would be worth making a post out of..

“Nice example, and I guess as I’ve been explaining everything that’s wrong with averages I should have been more careful in my explanation.

We will consider a real earth with an albedo..”

Absorbed Solar Radiation

The absorbed solar radiation has an average of 239 W/m2. This is averaged over the surface of the earth, which is 5.1 x 108 km2 = 5.10 x 1014 m2.

The incoming absorbed energy is therefore 1.2 x 1017 W.

Note: this average of 239 is a measured value of incoming – reflected solar radiation, divided by 4 for spatial geometry reasons, see The Earth’s Energy Budget – Part One. The total of 1.2 x 1017 W also equals the TSI of 1367 W/m2 x “disc area” of the earth x (1-albedo).

This is also currently the measured average outgoing longwave radiation (OLR) at the top of atmosphere, within instrument error.

The Hoovering

We’ll come to the energy-grabbing Latvia later (sorry Latvian’s wasn’t my idea).

It’s a typical earth in all other respects but a cosmic being has just “hoovered up” the trace gases like CO2, CH4, NO2 and turned water vapor into a non-absorbing gas. (If water vapor was also hoovered up the oceans and lakes would be a ready source of water vapor and within a month or two the atmosphere would have the same water vapor as before).

As a result radiation >4μm just goes right through it. That is the whole point about radiation – if nothing absorbs it, it keeps on going.

The radiation emitted from the earth just after the Hoover incident is 396 W/m2. Or, putting it another way, the total radiation emitted from the earth’s surface is 2.0 x 1017 W.

This total radiation is calculated by adding up the radiation from every square meter on the earth. And the average is simply the total divided by the area.

Note. In fact across a day and a year this value will change. Even year to year. So 2.0 x 1017 W is just the annual average across an appropriate time period. But it is appreciably higher than the absorbed solar 1.2 x 1017 W.

Energy Loss through Radiation and Climate Response

The net radiation loss from the planet starts at 0.8 x 1017 W = 2.0 x 1017 – 1.2 x 1017

Who knows what kind of climate response that would generate? And the time for the total response would also depend on how well-mixed the oceans were (because of their large heat capacity), but rather than trying to work out how long it will take, we can say that the earth will cool down over a period of time.

And no matter what happens to convection, lapse rates, and rainfall this cooling will continue. That’s because these aspects of the climate only distribute the heat. Nothing can stop the radiation loss from the surface because the atmosphere is no longer absorbing radiation. They might enhance or reduce the cooling by changing the surface temperature in some way – because radiation emitted by the surface is a function of temperature (proportional to T4). But while energy out > energy in, the climate system would be cooling.

Clouds and Ice Sheets

It’s possible (although unlikely) that all the clouds would disappear and in which case the net incoming – reflected radiation might increase, perhaps to 287 W/m2. (This value is chosen by measuring the current climate’s solar reflection of clouds, see Clouds and Water Vapor).

If that happened, total absorbed energy = 1.5 x 1017 W.

However, as the earth cools the ice sheets will increase and there’s no doubt that the albedo of the earth’s surface will increase so who knows what exactly would happen.

But it seems like the maximum absorbed solar radiation would at most go from 1.2 x 1017 W to 1.5 x 1017 W and more likely it would reduce below 1.2 x 1017 W.

A New Equilibrium

Eventually the outgoing radiation would approximately match the incoming radiation and temperature would settle around a value – this would take centuries of course, maybe 1000s of years..

And depending on the ice sheet extent and whether any clouds still existed the value of outgoing radiation might be around 1.0 – 1.5 x 1017 W. This upper value would depend on the ice sheets not growing and all the clouds disappearing which seems impossible, but it’s just for illustration.

Remember that nothing in all this time can stop the emitted radiation from the surface making it to space. So the only changes in the energy balance can come from changes to the earth’s albedo (affecting absorbed solar radiation).

And given that when objects emit more energy than they absorb they cool down, the earth will certainly cool. The atmosphere cannot emit any radiation so any atmospheric changes will only change the distribution of energy around the climate system.

What would the temperature of the earth be?

I have no idea.

But let’s pick the 1.2 x 1017 W as our average incoming less reflected solar energy, and so when “equilibrium” is reached the earth’s total surface radiation will be at this value. (Strictly speaking equilibrium is never truly the case, but we are considering the case where measured over a few decades the average outgoing radiation is 1.2×1017 W).

Uniform Temperature

Suppose that all around the world the temperature of the surface was identical. It can’t happen, but just to put a stake in the ground, so to speak.

Average outgoing radiation / surface area = 235 W/m2 – (that’s because I originally wrote down 1.2 x 1017 instead of 1.22 x 1017 and so the rounding error has caused a change from 239, but it doesn’t particularly matter, more a note for those in the “rounding police”).

And with a longwave emissivity close to 1 for most of the earth’s surface, this would be a temperature of 254K.

The Energy-Grabbing Latvians

As I mentioned before Latvians and Latvophiles, this wasn’t my idea. And anyway, it probably wasn’t your fault. I’ll adjust the commenter’s numbers slightly to account for the earth’s albedo.

In his example, mythical-Latvia has a surface area of 10,000 km2 = 1010 m2. And mythical-Latvia absorbs all of the energy with none left for the rest of the earth. The rest of the earth is at a temperature of 0K and Latvia is at a temperature of 5080K which means it radiates at 1.2 x 107 W/m2. Therefore the radiation from the whole earth = 1.2×1017 W and so the earth is in equilibrium (with the solar radiation absorbed), but the average temperature of the whole earth = 5080 * 1010 / 5.1×1014 = 0.1K.

Frosty.

And our commenter has nicely demonstrated the same point as in Lunar Madness and Physics Basics – you can have the same radiation from a surface with totally different average temperatures.

The Maximum “Average” Temperature

So we have had two approaches to calculating our equilibrium hoovered atmosphere, one with a temperature of 254K (-19°) and one with a temperature of 0.1K (-273°C) – both quite unrealistic situations it should be noted.

What’s the maximum “average” temperature? As already noted, at the wavelengths the earth radiates at (>4μ) it is quite close to a blackbody.

In this case, the maximum “average” temperature can’t be higher than what is known as the “effective blackbody temperature”, Teff.

This value, Teff, is a common convention to denote the effective radiating temperature of a body. This is just the temperature-radiation conversion from the Stefan-Boltzmann equation, Teff = (E/σ)1/4 – the rewritten version of the more familiar, E = σT4. It simply converts the energy radiated into a temperature. So 235 W/m2 = 254K.

It doesn’t mean, as already explained, that Teff is the “average” temperature. The “average” temperature (arithmetic mean) can be quite different from Teff, demonstrating that average temperature is a troublesome value.

I created confusion using the concept of Teff in my comment in the earlier article. By saying the earth would be at 255K without a radiatively absorbing atmosphere I really meant that in that situation the earth’s surface would be radiating (averaged globally annually) 239 W/m2.

The Earth Without an Absorbing Atmosphere

With conventions out of the way – if the atmosphere didn’t absorb any terrestrial radiation the radiation from the surface would slowly fall from its current annual global average of 396 W/m2 to around 240 W/m2.

The climate would undergo dramatic changes of course and no one can say exactly what the equilibrium “effective blackbody radiating temperature” would be as we don’t know how much solar radiation would be reflected in this new climate. Clouds, ice – and aerosols – all play a part in reflecting the solar radiation from the atmosphere and the surface, and if these change the amount of energy absorbed changes.

But without an atmosphere that absorbs longwave radiation there is no way that the radiation from the surface can be greater than the radiation from the top of the atmosphere. And that means that eventually the emission of radiation from the surface would be approximately equal to the absorbed solar radiation.

Therefore, the value of global annual average radiation might be 290W/m2 (unlikely), or it might be less than 239W/m2 (more likely).

The world would be much colder.

With an annual surface radiation of 239W/m², the “average temperature” would be  -18°C or colder.

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On a couple of unrelated articles on this blog, people have been asking questions about the moon. This is because a lot of people have read an article called A Greenhouse Effect on the Moon from www.ilovemycarbondioxide.com that makes some confused claims.

The article starts:

We’ve been told that the earth’s surface is quite a bit warmer than calculations predict. Theory has it that heat-trapping “greenhouse gases” account for a 33° Celsius disparity. But it turns out that our airless moon is also quite a bit warmer than predicted.

And finishes with:

The Earth is not “unusually” warm. It is the application of the predictive equation that is faulty. The ability of common substances to store heat makes a mockery of blackbody estimates. The belief that radiating trace gases explain why earth’s surface temperature deviates from a simple mathematical formula is based on deeply erroneous assumptions about theoretical vs. real bodies.

A long time ago a friend told me that the way the Bank of England trains people to spot counterfeit notes is to give them real notes to spend time getting used to the feel, texture, weight and so on. They don’t give them lots of counterfeits because it’s not as effective.

I have no idea if the story is true but I always thought that it was a useful concept for approaching any subject. Best to spend the time helping people understand the real theory – as all scientific “facts” are called – rather than spend 5% of the time on the real theory and introduce them to 19 flawed theories.

Therefore, most of this article will focus on building understanding of the basics rather than pointing out the many flaws in the article. We will look at the temperature of a moon-like body by way of very simple models.

These models are in Excel because it’s quick and easy.

The Model

The concept is very simple. This is an idealized moon-like surface for illustration.

For my moon-like body, we will consider one square meter of surface. This is because lateral heat flow within the surface will be extremely low and so we don’t want or need to build a GCM to solve this problem.

Solar radiation is absorbed by this surface and heats up. The surface has a definite heat capacity which we vary in the model to see how the results change.

The sun moves slowly through the sky so the amount of solar radiation incident on the surface varies over the course of the lunar “day”. The surface has an “absorptivity” for solar radiation – the proportion of solar radiation absorbed vs the proportion reflected.

When the sun is directly overhead the solar radiation incident is 1367 W/m2 and when the sun is on the horizon the solar radiation is zero – then for the whole “night” the radiation stays zero. Therefore, I’m considering the “equator”.

For reasons of laziness I set the lunar day to be 28 days, but the exact value doesn’t matter.

And the absorptivity was set to 0.9 (which means 90% of incident solar radiation is absorbed and 10% is reflected). Also the emissivity was set to the same value, but in this example it could be different. With different values similar results would occur but with different equilibrium temperatures. See Note 1.

The simple maths for the model is at the end of the post as many people don’t like seeing equations.

The Results

Now, if the surface had no heat capacity (or as mathematicians might say, “as the heat capacity tends to zero”) then the surface would instantaneously heat up until the radiation emitted matched the absorbed radiation.

So in that unrealistic case, the temperature would follow this curve:

 

Moon-like surface, zero heat capacity

Moon-like surface, zero heat capacity

 

So during the moon-like night, the surface drops immediately to absolute zero, and during the “day” the emission of radiation exactly matches the absorption. (For mathematically inclined readers this follows a cos θ relationship – see maths section at end).

Note that this isn’t like the earth or any real body. It’s just a useful thought experiment to show what would happen if the surface had no heat capacity.

Under this condition:

  • absorption of solar radiation = 391.7 W/m2 (averaged over many cycles)
  • emission of lunar radiation = 391.7 W/m2 (averaged over many cycles)
  • mean temperature = 169.3K
  • min temperature = 0K
  • max temperature = 394K

Energy in = energy out – so no surprises there.

Let’s start increasing the heat capacity and see what happens – per m2, 10,000J/K heat capacity:

 

Moon-like surface with 10,000 J/K heat capacity per m^2

Moon-like surface with 10,000 J/K heat capacity per m^2

 

  • absorption of solar radiation = 391.7 W/m2 (averaged over many cycles)
  • emission of lunar radiation = 391.7 W/m2 (averaged over many cycles)
  • mean temperature = 195.3K
  • min temperature = 38K
  • max temperature = 397K

Per m2, 50,000J/K heat capacity:

 

Moon-like surface with 50,000 J/K heat capacity

Moon-like surface with 50,000 J/K heat capacity per m^2

 

  • absorption of solar radiation = 391.7 W/m2 (averaged over many cycles)
  • emission of lunar radiation = 391.5 W/m2 (averaged over many cycles)
  • mean temperature = 211.3K
  • min temperature = 64K
  • max temperature = 394K

Per m2,  500,000J/K heat capacity:

 

Moon-like surface with heat capacity = 500,000 J/K per m^2

Moon-like surface with 500,000 J/K heat capacity per m^2

 

  • absorption of solar radiation = 391.7 W/m2 (averaged over many cycles)
  • emission of lunar radiation = 390.0 W/m2 (averaged over many cycles)
  • mean temperature = 247.7K
  • min temperature = 133K
  • max temperature = 393K

Per m2,  5,000,000J/K heat capacity:

 

Moon-like surface, 5,000,000 J/K per m^2

Moon-like surface, 5,000,000 J/K per m^2

 

  • absorption of solar radiation = 391.7 W/m2 (averaged over many cycles)
  • emission of lunar radiation = 391.7 W/m2 (averaged over many cycles)
  • mean temperature = 290.9K
  • min temperature = 247K
  • max temperature = 342K

Hopefully, for most people, the fact that the temperature range is reducing as heat capacity increases is reasonably intuitive. If you want to heat up a cupful of water it takes less time than heating a swimming pool. If you want to cool down both through the same surface area it will take longer for the swimming pool to cool down.

Summary of Results

Notice that in each case the average value of absorption = emission – to within 1%.

The 1% is just a result of imperfect starting conditions. If the chosen simulation starting temperature was exactly right, or there were enough “spin up” cycles to get into the steady state before the averaging was done then the absorption = emission exactly.

It’s probably not surprising to anyone that absorption = emission over a set number of cycles because otherwise the overall trend in temperature would be increasing or decreasing.

Next a plot of mean, min and max temperature as the heat capacity increases, note the log axis for heat capacity:

The reason for plotting the heat capacity on a “log” or logarithmic axis was because the heat capacity is increased by a an order of magnitude each time. Linear plots make the results of this kind of simulation less clear.

The mean temperature is simply the arithmetic average of temperature over every single time step. (All the numbers added up and divided by the number of results).

So the mean temperature does increase when the surface has an increased heat capacity!

It looks like the ilovemyco2 writers were correct and the whole greenhouse effect was just a result of heat capacity of the oceans and land.

Time for me to pack my bags and head off into the sunset..

But wait, hold on a minute..

There’s something very strange going on. The temperature is increasing, but the average emission of radiation has stayed exactly the same:

How can temperature increase without the radiation increasing? Radiation is emitted in proportion to the 4th power of temperature – for a blackbody (ε=1), E = σ . T4, where σ = 5.67×10-8

If the temperature goes up, radiation must go up as well. Is there something wrong with the model?

No. And for those who’ve read Why Global Mean Surface Temperature Should be Relegated, Or Mostly Ignored this example won’t be surprising.

Take 3 “temperatures”:  1, 10, 100.

Now we average them -> average = 111/3 = 37K

And calculate the energy radiated, E = 37 4 x 5.67×10-8 = 1,874,161 x 5.67×10-8 = 0.11 W/m2

Alright, let’s do it the other way. Let’s calculate the energy radiated for each temperature:

  • 14 x 5.67×10-8 = 1 x 5.67×10-8 = 5.67×10-8
  • 104 x 5.67×10-8 = 10,000 x 5.67×10-8 = 5.67×10-4
  • 1004 x 5.67×10-8 =100,000,000 x 5.67×10-8 = 5.67

And now average the energy radiated -> average = (5.6705670567/3) = 1.89 W/m2

One method gives 18x the other method – how can this be and which one is right?

Just for the many people would prefer to see the calculation without the Stefan-Boltzmann constant of 5.67×10^8 everywhere – in that case we compare 374 = 1,874,161 with the alternative method of (14 + 104 + 1004)/3 = 100,010,001/3= 33,336,667

Also (of course) a factor of 18 between the two methods of calculating the “average”.

There’s nothing surprising about this – average a series of numbers and raising the average to the 4th power will almost always give a different answer to first calculating the 4th power for each of a series of numbers and averaging the results.

Now the moon has some extreme temperature ranges in the examples shown and, therefore, the “mean” temperature changes significantly.

The earth by contrast, with less extreme temperatures has this result –

  • the “average” temperature = 15°C, and converting that to the “average” radiation = 390 W/m2
  • calculated the correct and painful way, the individually calculated values of radiation from each and every surface temperature around the globe every few hours over a year.. then averaged = 396 W/m2

Conclusion

So the reason that the moon – with a surface with a real heat capacity – appears to have a warmer climate “than predicted” is just a mathematical error. A trap for the unwary.

The right way to calculate a planet’s average radiation is to calculate it for each and every location and average the results. The wrong way is to calculate the average temperature and then convert that to a radiation. In the case of the earth’s surface, it’s not such a noticeable problem.

In the case of the moon, because of the wide variation in temperature, the incorrect method produces a large error.

So there’s no “lunar explanation” for the inappropriately-named “greenhouse” effect.

In the case of the earth there is anyway a huge difference from the moon. The solar radiation absorbed at the top of the earth’s atmosphere – about 240W/m2 is approximately balanced by the outgoing longwave radiation of the same amount. But the radiation from the surface of the earth of 396W/m2 is much larger than this top of atmosphere value of 240W/m2.

That’s the greenhouse effect.

But ilovemyco2 – hats off to you for enthralling and exciting so many people with a simple mathematical puzzle.

Maths in the Model

Ein = S . cosθ . α   – for -90° < θ < 90°

Ein = 0   otherwise

where Ein = energy absorbed by the surface in J/s, S = the solar irradiance in W/m2, θ = angle of the sun from the zenith, α = absorptivity of the surface at the solar radiation wavelengths.

Eout = ε . σ . T4

where Eout = energy radiated by the surface in J/s, ε = emissivity of the surface at the wavelengths it is radiating at, σ = 5.67 x 10-8, and T is the temperature in K (absolute temperature). This is the Stefan-Boltzmann equation.

and for each time step, Δt:

ΔT = (Ein – Eout)/C

where C = heat capacity of a 1m2 surface in J/K and ΔT is the change in temperature.

For people who like even more detail:

The assumption is that the conductivity of heat into the surface is very high with some kind of insulating layer below the “heat capacity” layer. This makes the calculation slightly easier to understand than using thermal diffusivity.

And the conductivity of heat laterally is very low to avoid considering thermal equalization between adjacent surfaces.

Neither of these assumptions has any significant effect on the “experiment”, or on the principles that it demonstrates.

Note 1

Emissivity and absorptivity are inherent properties of the material in question and are wavelength dependent. In the case of a surface like the earth, the surface receives solar radiation centered around 0.5μm and radiates out with wavelengths centered on 10μm. See, for example, The Sun and Max Planck Agree. So there is no reason to expect that absorptivity = emissivity (because we are considering the properties at different wavelengths).

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Checkout the more comprehensive: The Sun and Max Planck Agree – Part Two

For regular readers of this blog, this post adds nothing new. Think of it as placeholder – a link to send people to when they ask about this basic subject.

A very handy aspect of climate science is that we can easily differentiate between solar (from the sun) radiation and terrestrial (from the earth) radiation. We can do this because emission of radiation changes with wavelength and depends on the temperature of the body radiating:

 

Radiation vs Wavelength -Sun and Earth

Radiation vs Wavelength - Sun and Earth

 

Picture the scene, if you will.

The climate science enthusiast explains that the sun heats the atmosphere and the surface of the earth – both land and sea. And everyone agrees. Of course some solar radiation is reflected and no one disputes it.

The climate science enthusiast explains that the earth, when heated up by the sun, emits thermal radiation which is upward radiation (of course). And everyone agrees.

The climate science enthusiast explains that the atmosphere absorbs some terrestrial radiation, heats up and emits thermal radiation in all directions – some of it downward. Many are not so sure.

You are mixing up solar radiation with this ‘back-radiation’ from the atmosphere. Please provide data from night-time only.

This has been a theme on many other blogs and in many comments on Science of Doom so it’s worth pulling together the basics.

Max Planck and Blackbody Radiation

Max Planck was awarded the Nobel Prize in 1918 for his contributions to science, including this gem about radiation:

 

Spectral Intensity, Max Planck

Spectral Intensity, Max Planck

 

This equation describes the spectral intensity of a “blackbody” as a function of temperature (absolute temperature) and wavelength.

The values of h, k and c0 are constants. T is absolute temperature and λ is wavelength.

If we plot the result of this equation for a temperature of 5780K – the sun – we get a graph which looks remarkably like the radiation we actually measure from the sun outside the atmosphere.

That’s a good thing, and Max won’t have to hand back his Nobel prize:

 

Solar Radiation and the Blackbody Curve for 5780K, Incropera (2007)

Solar Radiation and the Blackbody Curve for 5800K, Incropera (2007)

 

This is from Incropera and DeWitt – for those suspicious of everything produced by climate science, a work untouched by climate scientists – which goes by the enthralling name of Fundamentals of Heat and Mass Transfer and is now in its sixth edition.

From climate science itself, from Professor F.W. Taylor of Oxford University, from Elementary Climate Physics (2005):

 

Solar Radiation, top of atmosphere and at earth's surface, Taylor (2005)

Solar Radiation, top of atmosphere and at earth's surface, Taylor (2005)

 

Much the same. And it gives us confidence that Max Planck was right. In which case we can calculate some key parameters about the radiation from the sun and from the earth.

Solar vs Terrestrial Radiation

Solar radiation at 5780K has a few interesting properties which are easily calculated using the equation above. You can put the equation into excel and work it out for yourself.

Or you can use spectralcalc.com to do the heavy lifting. With spectralcalc just select a temperature and at the bottom select an “Upper limit” and “Lower limit” of wavelength. This will calculate the spectral intensity between these two wavelengths using Planck’s equation. Don’t forget to make sure you divide this Band Radiance by the Radiance, and not the Radiant emittance (check the units to make sure you are comparing like with like).

Some important results from Max and from the sun..

As a proportion of total solar irradiance:

  • Total energy from 0 – 0.75μm                54%   – all energy up to infra-red
  • Total energy from 0.39μm – 0.75μm      43%   – visible light only
  • Total energy from 0 – 4μm                   99%   – all “shortwave”
  • Total energy from 4-infinity                       1%   – all “longwave”
  • Total energy from 13μm-infinity              0.03% – major 15μm CO2 band and above

Terminology:

  • >0.75μm is infra-red (slightly different conventions exist about the maximum value for visible light, but nothing substantial)
  • 0-4μm is “shortwave” – a climate science convention referring to solar radiation
  • 4μm-infinity is “longwave“- a climate science convention referring to terrestrial radiation

For various temperatures of the earth’s surface, the proportion of its radiation which is in the “longwave” band (4μm and above):

  • 15°C (288K) – 99.9%
  • -50°C (223K) – 99.99%
  • 50°C (323K) – 99.6%

The last important point to consider is that sometimes people get confused about the relative magnitude of solar and terrestrial radiation – for example, with the first graph in the post the solar radiation is much higher than the terrestrial radiation. But this is because the solar radiation in that example is the value close to the surface of the sun. But the earth only receives about one two-billionth of the solar radiation due to its distance from the sun.

Overall, and on average, the solar energy into the atmosphere is of a similar magnitude to the terrestrial radiation out of the atmosphere. (Otherwise the earth would heat up or cool down very quickly).

But in any one location on any given day it is possible for the solar radiation to vary from zero (night-time) to potentially over 1000 W/m2 (sun overhead on a cloudless sky). The absolute maximum is the total solar irradiance of 1367 W/m2 – this would be the case if the sun was directly overhead and the atmosphere reflected or absorbed nothing, which is never the case, but let’s consider this condition to get an idea of the maximum possible solar radiation in the longwave.

With the sun directly overhead and no atmospheric reflection or absorption we would have:

  • 13.7 W/m2 > 4μm
  • 4.1 W/m2 > 6μm
  • 0.4 W/m2 > 13μm
  • 0.25 W/m2 in the CO2 band of 13μm – 17μm

Conclusion

Well, hopefully everyone can see that even though the radiation spectrum by wavelength for any radiating body extends to infinity, the amount of solar radiation which is >4μm is 1% and the amount of terrestrial, or longwave, radiation which is <4μm is much less than 1%.

  • This means, if we measure radiation with a wavelength of >4μm it is not from the sun, even if it is daytime (to a 96 – 99% accuracy).
  • And if we measure radiation with a wavelength of >13μm it is not from the sun, even if it is daytime (to greater than 99.9% accuracy).

That is, unless Max Planck and the sun are wrong.

If you think this explanation or conclusions are wrong in any way then stay on this post and ask questions or explain what is wrong with it. Because if this basic element is confusing it will be difficult to make any progress in understanding climate science.

Update – followup article – The Sun and Max Planck Agree – Part Two

Read Full Post »

In Radiation Basics and the Imaginary Second Law of Thermodynamics I covered a fair amount of ground because it started in answer to another question/point from a commenter.

We all agree that the net effect of radiation between hot and colder bodies is that heat flows from the hotter to the colder body, but many people have become convinced that this means radiation from a colder body has no effect on a hotter body.

After explaining a few basics about emission and absorption, I concluded:

Therefore, there is no room in this theory for the crazy idea that colder bodies have no effect on hotter bodies. To demonstrate the opposite, the interested student would have to find a flaw in one of the two basic elements of thermodynamics described above.

And just a note, there’s no point reciting a mantra (e.g., “The second law says this doesn’t happen”) upon reading this.

Instead, be constructive. Explain what happens to the emitting body and the absorbing body with reference to these elementary thermodynamics theories.

One of our regular commenters has finally explained what happens.

This was a great day of joy because in three other articles on this blog (The Imaginary Second Law of Thermodynamics, How Much Work Can One Molecule Do? and On the Miseducation of the Uninformed by Gerlich and Tscheuschner (2009)) and one on another blog the subject has been much discussed.

I have asked many many times:

What happens to radiation from the colder body when it “reaches” the hotter body?

But I had never been given an answer – until now. (Note: the general consensus from the imaginary second law advocates – as much as I can determine – is that the colder body does emit radiation so at least there is agreement on the first step).

Finally, the answer is revealed:

Back to thermodynamics and electromagnetic radiation.
Scienceofdoom and others think that the hot surface has no option but to absorb a photon from the cold surface.
I think a lot of this radiation is in fact scattered from the hot surface and is not absorbed.

“A Lot” is Not Absorbed?

Before we dive into the fascinating topic of absorptivity and absorption, I hope people don’t think I am being pedantic for drawing attention to the fact that one of our most prominent advocates of the theory (the Imaginary Second Law) has actually failed to support it.

Science is about detail.

If no radiation from the colder body is absorbed by the hotter body then the imaginary second law stands. That is, if any radiation emitted by a colder body “reaches” the hotter body and is absorbed by the hotter body then the colder body has transferred energy to the hotter body.

The colder body has had “an effect”.

It’s hard to be certain about the imaginary second law of thermodynamics because I can’t find it in a text book. In fact, on another note, it has been a day of double joy, because another imaginary second law advocate stepped up to the plate when presented with this from a thermodynamics textbook:

 

From "Fundamentals of Heat and Mass Transfer, 6th edition", Incropera and DeWitt (2007)

From "Fundamentals of Heat and Mass Transfer, 6th edition", Incropera and DeWitt (2007)

 

And said:

It is absolutely in error.

Which was wonderful to hear because up until now everyone else had simply ignored the question as to whether Incropera and DeWitt didn’t understand the basics of radiation (for reasons that are all too easy to imagine).

But I digress.

I can’t be 100% certain what the imaginary second law of thermodynamics teaches but it has appeared up until now – from the comments by many advocates – that colder bodies have no effect on hotter bodies.

How can it be that the first time someone explains what happens to the incident radiation they agree, at least in principle, with the rest of the world? We (the rest of the world) all think that cold bodies have an effect on hotter bodies.

Perhaps more advocates can comment and vote on this idea..

[Stop press – after writing this a newer entrant to the field has promoted a new idea but this one can wait until another day]

Absorptivity and Absorption

There are a few basic concepts in traditional thermodynamics that are worth explaining, even though they might appear a little tedious.

I was already thinking about writing an article on this after I had earlier explained:

According to Kirchoff’s law, emissivity = absorptivity for a given substance at the same wavelength (and for some surfaces direction needs to be defined also).

And the same commenter responded:

You have a particularly naive view of heat transfer.

When a green plant absorbs some em radiation to make starch does it simultaneously emit the same radiation?

You have not grasped the fact that if the absorption of 4um radiation was exactly balanced by the emission of 4um radiation the net effect would be zero.

Which would shoot a massive hole in the case for AGW.

I prefer to think of my understanding of physics as traditional rather than naive. So, a few basics need explaining so that readers can judge for themselves.

Just a comment, as well, for new people looking into this subject. The basics often seem a little dull, but hopefully I can persuade a few to dig deep and work hard to get the very basics clear. I can promise unrelenting joy down the track as you realize that you understand more than most other people who had jumped ahead and are now writing confused comments.. (assuming this will give you unrelenting joy).

Let’s look at snow in sunlight and use it to “shed light” on a dull subject.

First of all, there are two important factors involved in the absorption of radiation:

  • the radiation incident on the snow (i.e., the radiation value as a function of wavelength)
  • the absorptivity – the property of the snow (as a function of wavelength) which determines how much radiation is absorbed and how much is reflected

We will focus on the snow being heated by sunlight and ignore terrestrial radiation – even though the material will also be heated by terrestrial radiation. This is because we aren’t trying to work out a complete energy balance for this particular material, just illustrating the important points.

Solar radiation has a spectrum which looks something like this:

 

Solar radiation at top of atmosphere and the earth's surface, Taylor (2005)

Solar radiation at top of atmosphere and the earth's surface, Taylor (2005)

 

This shows how the radiation incident on the snow varies with wavelength. The actual amplitude is dependent on the time of day, the latitude, the amount of clouds, and so on.

The important point is that radiation from the sun peaks at a wavelength of around 0.5μm and above 2μm is much reduced (91% of solar radiation is below 2μm). Therefore, to find out how much radiation the material actually absorbs we need to know the absorptivity at these wavelengths.

Here are some examples of reflectivity and absorptivity of various materials across quite a wide spectral range:

 

Reflectivity vs wavelength for various surfaces, Incropera (2007)

Reflectivity vs wavelength for various surfaces, Incropera (2007)

 

The scale on the left is reflectivity and on the right (harder to see) is absorptivity from 1.0 at the bottom up to 0.0 at the top.  Absorptivity = 1-reflectivity.

Absorptivity is a function of wavelength and is the proportion of incident radiation at that wavelength which is absorbed.

Absorptivity is an inherent property of that material

Let’s take snow as an example. Sunlight on snow will be mostly reflected and not absorbed. That’s because the incident sunlight is mostly between 0.2μm to 2μm – and if you check the reflectivity/absorptivity graph above you will see that the absorptivity is quite low (and reflectivity quite high).

Snow has a high albedo for sunlight – around 60% – 80% is reflected, meaning only 20%-40% is absorbed.

Now let’s consider the snow at a temperature of 0°C (273K). How much thermal radiation does it emit?

If it was a blackbody, it would emit radiation as the Planck function at 273K:

 

Blackbody radiation at 273K (0'C)

Blackbody radiation at 273K (0'C)

 

The first thing you notice is that the snow is radiating at completely different wavelengths to the solar radiation. The solar radiation is mostly between 0.2μm to 2.0μm, while the snow is radiating between 5μm and 50μm.

So we need to know the emissivity between these wavelengths to work out the actual emission of radiation from the snow. Emissivity is a value between 0 and 1 which says how close to a blackbody the material is at that wavelength. Emissivity is equal to absorptivity – see the next section – so we can just look up the absorptivity instead.

In the graph from Incropera the absorptivity of snow at higher wavelengths is not shown. But it’s clear that it has changed a lot (and in fact absorptivity is very high – and reflectivity very low – at these higher wavelengths, which climate scientists call “longwave”).

Kirchhoff’s Law

Kirchoff’s law says that emissivity = absorptivity as a function of wavelength – and sometimes direction. That is, these two intrinsic properties of any material have the same value at any wavelength. (The derivation of this formula isn’t something that will be discussed here).

Kirchoff didn’t say that emission = absorption

That’s because emissivity is not the same as emission. And absorptivity is not the same as absorption.

Of course, if a body is only gaining and losing energy by radiation (i.e., no conduction or convection), and the body is not heating up or cooling down then absorption will equal emission. This is due to the first law of thermodynamics or conservation of energy.

But if absorption increases, the body will heat up until the new value of emission balances the increase in absorption. However, the absorption might be in one wavelength range and the emission in a totally different one.

It’s not so difficult to understand, but it does require that you grasp hold of the basics.

So (digressing) back to our commenter, it’s clear that his “reasons” for ditching Kirchhoff’s law weren’t because Kirchhoff was wrong..

And Kirchhoff’s law is very strong. It would need a monumental effort to overturn this part of thermodynamics basics. Reasonable people might expect that if over-turning Kirchhoff’s law is necessary to support the imaginary second law of thermodynamics, then this might imply that the imaginary law is, well, imaginary..

However, even stranger concepts are necessary to support the imaginary second law.

Would Sir like to Absorb this Radiation? No? Very Good Sir, I’ll take it Back.

Now that we have covered a few basics, perhaps some points might start to make sense.

And perhaps this comment might seem a little flawed:

Back to thermodynamics and electromagnetic radiation.
Scienceofdoom and others think that the hot surface has no option but to absorb a photon from the cold surface.
I think a lot of this radiation is in fact scattered from the hot surface and is not absorbed.

Let’s examine the idea that radiation from the cold surface is “not absorbed”, and see it in its comedic glory.

Consider a surface of 0°C (273K).

And now consider one body at 10°C radiating towards this 0°C surface. According to the imaginary second law advocates the radiation from the 10°C body is accepted.

Now consider a similar scenario but the 10°C body has been replaced with a
-10°C body. According to the imaginary second law advocates the radiation from the colder -10°C body is not accepted. And according to its strongest advocate, “it is scattered and not absorbed“.

Here is the comparison spectrum for the two radiating bodies:

 

Blackbody radiation curves for -10'C (263K) and +10'C (283K)

Blackbody radiation curves for -10'C (263K) and +10'C (283K)

 

Notice the very similar radiation curves.

And remember that absorptivity is simply a function of the material receiving the radiation.

And ask yourself, how can the 0°C surface reflect the 10μm radiation from the colder -10°C body, and yet absorb 10μm radiation from the hotter +10°C body?

If the absorptivity at 10μm is 0.9 then it will accept 90% of the radiation at this wavelength from a +10°C body and 90% of the radiation at this wavelength from a -10°C body. It can’t check the menu and “send it back”.

Likewise for each wavelength in question.

[By the way, the fact that the body at -10°C emits radiation that is absorbed by the 0°C surface doesn’t mean that the real second law of thermodynamics is violated. Simple, the 0°C surface is also radiating, and at a higher intensity than the -10°C surface. The net is from the hotter to the colder.]

Conclusion

It took many many requests to finally hear the explanation as to why radiation from a colder body has no effect on a hotter body.

It’s not an explanation that will stand the test of time – except for the wrong reasons. It requires the advocate to believe amazing things about materials. Perhaps that’s why it took so long to get the answer.

Yet more ridiculous ideas have recently been proposed. All in the cause of supporting the imaginary second law of thermodynamics. (These need considering in another post).

Just a digression on the perpetual motion machine (because I don’t want to write a whole post on it). For some reason, perhaps the Gerlich and Tscheuschner miseducation, many confused people think that the absorption and re-emission of longwave radiation by the atmosphere constitutes a perpetual motion machine – and therefore this proves the inappropriately-named “greenhouse” effect can’t exist! Well, we all agree that there is no perpetual motion machine.

But why would the atmosphere radiating towards the earth constitute “perpetual motion”?

Think for a minute before answering, if you claim this.

Right now the earth is around the same temperature it was 100 years ago and also 1000 years ago. Is that a perpetual motion machine – a machine that can’t exist? No. The sun warms the earth. And the sun is powered by internal reactions.

Ok. So if the sun turns off what happens? The earth cools down.

For people who think that the earth’s surface is radiating towards the colder atmosphere, and the colder atmosphere is radiating less energy back towards the earth, and the earth is absorbing this radiation.. we expect the same thing to happen when the sun turns off. The earth will cool down. Just a little slower.

No perpetual motion machine.

Well, the second law of thermodynamics is quite a basic one but misunderstood by many who think they are supporting it.

For newcomers to this debate the approach I have taken is to take a specific example and ask the advocates of their theory how specific well-understood physical properties can possibly support their argument. Mostly I get no response.

I have finally had two answers. One is considered here and it’s hard to understand how anyone can believe it.

See the followup article – The First Law of Thermodynamics Meets the Imaginary Second Law

And the later article – The Real Second Law of Thermodynamics

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This post will suffer from the unfortunate effect of too much maths – something I try to avoid in most posts and certainly did in The Imaginary Second Law of Thermodynamics. It’s especially unfortunate as the blog has recent new found interest thanks to the very kind and unexpected words of Steve McIntyre of Climate Audit.

However, a little maths seems essential. Why?

Some of the questions and triumphant points some commentators have made can only be properly answered by a real example, with real equations.

It’s something I commented on in American Thinker Smoking Gun – Gary Thompson’s comments examined, where I explained that a particular theory is not usually a generalized statement about effects but rather a theory is usually a set of mathematical equations to be applied under certain well-defined circumstances.

In The Imaginary Second Law of Thermodynamics the example was of a sun radiating into the nothingness of space, when a new star was brought into the picture. And the new star was hotter. So the question was, would the radiation from the colder star actually have an effect on the hotter star.

Some Gerlich and Tscheuschner apostles thoughtfully spent some time trying to enforce some discipline about terminology of heat vs energy and whether radiation was a vector – but forgot to answer the actual question.

Recently a commentator suggested that the real answer lay in considering two stars of equal temperature which were brought into proximity.

As for the sun and the other star, only the sun at T10,000 will go up in T if you insert another T11,000 star, never mind how hard one thinks about it. Maybe this becomes obvious once you make the sun and the new star equally hot at T10,000 . They don’t become both hotter, which is what is predicted in the thought experiment. If the sun heats up the newly inserted star it should not matter really if that new star is at T11,000 or T10,000 does it?

And I said:

Unless all of the radiation is reflected it will increase the surface temperature. It might be 0.1K, 1K, 0.0001K – it all depends on the W/m^2 at that point – and the absorptivity at the wavelengths of the incident radiation.

If that isn’t the case, then you have a situation where incident radiation is absorbed but has zero effect.

And our commentator responded:

Congratulations on sticking with it! I think you just discovered the endless source of energy we are all so desperately looking for. When you expect two equally hot bodies to keep heating each other, where is the limit? and could we not syphon off some off that excess heat.

Which bring us to here. Many people gets confused around these basic points, which is why we need a post with some maths. The maths can prove the point, unlike “talk”.

Conceptual understanding is what everyone seeks. I hope that this article brings some conceptual understanding even though it has a core maths section.

Some Unfortunate but Necessary Maths

Let’s first of all consider one “star” out in the nothingness of space.

The star has a radius of 1000m (1km) and a temperature of 1000k (727°C). This temperature is identical all over the surface and is powered from internal stellar processes. This internal heat generation is constant and not dependent on any changes in surface temperature. We will also assume – only necessary for the second part of the experiment – that the thermal conductivity of this star is extremely high. This means that any radiation absorbed on one part of the surface will conduct rapidly around the surface of the star – to avoid any localized heating.

We also assume that its emissivity is 1 – it is a blackbody across all wavelengths.

A few derived facts about this star, which we will give, in true mathematical style, the exotic name of “1”.

Surface area:

A1 = 4πr2 = 1.256×107m2

Flux from the surface of star 1, from the Stefan-Boltzmann equation:

F1 = εσT4 = 1 x 5.67×10-8 x 10004 = 56,700 W/m2

How the radiation emission varies with wavelength:

Total thermal energy radiated:

E1 = A1. F1 = 7.12 x 1011W

If this is the thermal energy radiated, and star 1 is at equilibrium, then the heat generated within the star must also be this value. After all, if the heat generated was higher then the star’s surface temperature would keep increasing until steady state was reached.

For example, if the internal energy source increased its output (for some reason) to 8 x 1011W then the output of the star would eventually reach this value. So F1(new) = 8 x 1011/A1 = 6.37 x 104 W/m2

And from the Stefan-Boltzmann equation, T = 1,030K. Just an example, for illustration.

And now, two stars brought into some proximity

So what happens when two identical stars are brought into some proximity? According to our commentator, nothing happens. After all, if “something” happens, it can only be thermal runaway.

The only way we can find out is to use the maths of basic thermodynamics. For people who go into “fight or flight” response when presented with some maths, the conclusion – to relieve your stress – is that the system doesn’t go into thermal runaway, but both stars end up at a slightly higher temperature. Deep breaths. See a later section for “conceptual” understanding.

We define E1 = the energy from star 1 before star 2 (an identical star) appears on the scene.
And E1‘ = the energy from star 1 after star 2 appears on the scene.

The distance between the two stars = d

The radius of each star (the same) = r = 1000m

Consider star 2, radiating thermal energy. Some proportion of star 2’s thermal radiation is incident on star 1, which has an absorptivity (= emissivity) of 1.

To calculate how much of star 2’s thermal radiation is incident on star 2, we use the very simple but accurate idea of a large sphere at radius d from star 2. This large sphere has a surface area of 4πd2.

On this large sphere we have a small 2-d disk of area πr2, which is the area projected by the other star on this very large sphere. And so the proportion of radiation from star 2 which is incident on star 1:

b = πr2 / 4πd2 = r2 / 4d2 [equation 1]

This value, b, will be a constant for given values of r and d.

So, our big question, when star 2 and star 1 are “wheeled in” closer to each other, at a distance d from each other – what happens?

Well, some of star 2’s radiation is incident on star 1. And some of star 1’s radiation is incident on star 2.

Will this – according to the crazy theories I have been promoting – lead to thermal runaway? Star 1 heats up star 2, which heats up star 1, which heats up star 2.. thermal runaway! The end of all things?

Thermal Runaway? Or a Slight Temperature Increase of Both Stars?

To work out the answer, it’s all about the maths. Not that the subject can’t be understood conceptually. It can be. But for those who are convinced this is wrong, “conceptual” just leads to “talk”. Whereas maths has to be disputed by specifics.

When our two stars were an infinite distance from each other in the vastness of space, E1 = E2 – with the values calculated above.

Now that the two stars are only a distance, d, from each other, a new source of thermal energy is added.

Consider star 1. If this star absorbs thermal radiation from elsewhere, it must emit more radiation or its temperature will rise. If its temperature rises then it will emit more radiation. (See note 1 at end).

So:

E1‘ = E1 + E2‘ b   [equation 2]

E2‘ = E2 + E1‘ b   [equation 3]

This is simply showing mathematically what I have already expressed in words.

And because the stars are identical:

E1 = E2 [equation 4],  and

E1‘ = E2‘   [equation 5]

So, from [2] and [4],  E1‘ = E1 + E1‘ b, or (rearranging):

E1 = E1‘(1-b), so E1‘ = E1 / (1-b)   [equation 6]

So once new equilibrium is reached, we can calculate the new radiation value, and from the Stefen-Boltzmann equation, we can calculate the new temperature.

These equations don’t tell us how long it takes to reach equilibrium, as we don’t know the heat capacity of the stars.

Let’s put some numbers in and see what the results are:

Let d=1000km = 1,000,000m or 1×106m

Therefore, from [1]:

b =10002/4x(1×106)2

b = 2.5×10-7

And, from [6]:

E1‘ = E1/0.99999975 = 1.00000025 E1

Do we even want to work out the change in temperature required to increase the radiation from the star by this tiny amount? Just for interest, the new surface temperature = 1000.00006 K

But this is the new equilibrium for both stars.

Note that there is no thermal runaway.

The approach can now be subject to criticism. (So far no one has checked my maths, so it’s quite likely to have a mistake which changes the numerical result). I can’t see how there can be a mistake which would change the main result that no thermal runaway occurs. Or that would change the result so that no change in temperature occurs.

For more interest, suppose the stars were only 10km or 10,000m apart. Strictly speaking, while the distance between the stars is “much greater” than the radius of the stars we can use my equations above. The mathematical expression for this “much greater” is, d>>r. Once the stars are close enough together the maths gets super-complicated. This is because the distance from one point on one star to one point on another star is no longer “d”. For example, as a minimum it will be d-2r (the two closest points)

No one wants to see this kind of “integral” (as the required maths is called). Least of all, me, I might add.

Well, we’ll ignore the complexities and how it might change the result, just to get a sense of roughly what the values are.

If d=10,000, b=0.0025 and so E1‘ = E1 / 0.9975 =  1.0025 E1

Consequently the change in surface temperature to increase the temperature by this amount, T=1000.6K

Not very exciting, and still no thermal runaway.

Conceptual Understanding and Some Radiation Theory

Understanding this conceptually for most people won’t be too difficult. If you add energy to a body it will warm up. And it will emit more radiation. There will be a new equilibrium.

Two bodies doing this to each other will also just reach a new equilibrium – they can’t go into thermal runaway. Of course, no one believes that thermal runaway will result, least of all the person who made the original comment – that was their whole point. They just didn’t realize that a new equilibrium could exist. The only way I can prove it is mathematically.

Conceptual thinking is very valuable. Maths is very tedious. But because Gerlich and Tscheuschner have made such a huge contribution to the misunderstanding of basic thermodynamics it needs some extended explanation, including some maths.

Many people have got confused about the subject because

Heat flows from the hotter body to the colder body

We all agree.

Many people have taken the statement about heat flow and imagined that thermal radiation from a colder body cannot have any effect on a hotter body. This is where they go wrong.

A body with a temperature above absolute zero will radiate according to its emissivity (and according to the 4th power of temperature). This property is dependent on wavelength and sometimes on direction. The emissivity of a body is also equal to the absorptivity at these same wavelengths and directions.

The wavelength dependence of emissivity and absorptivity is very striking:

 

Reflectivity vs wavelength for various surfaces, Incropera (2007)

Reflectivity vs wavelength for various surfaces, Incropera (2007)

 

Absorptivity is the scale on the right from 1 at the bottom to zero at the top and is 1-reflectivity. (See note 2).

Here you can see that snow is highly reflective at solar wavelengths (shortwave) and absorbs little radiation, whereas it has a high absorptivity at longer wavelengths (and therefore does not reflect much longwave radiation).

The same goes for white paint. It reflects sunlight but absorbs terrestrial radiation.

The equation for how much radiation is emitted by a body – εσT4does not include any terms for where the radiation might end up. So whether this radiation will be incident on a colder or hotter body, it has no effect on the radiation from the source. (See note 3).

Similarly, when radiation is incident on a body the only factor which affects how much radiation is absorbed and how much radiation is reflected is the absorptivity of the body at that direction and wavelength. The body cannot put out traffic cones because the incident radiation has been emitted by a colder body.

This is elementary thermodynamics. Emissivity and temperature determine the radiation from a body. Absorptivity determines how much incident radiation is absorbed.

Therefore, elementary thermodynamics shows that a cold body can radiate onto the surface of a hotter body. And the hotter body will absorb the radiation – assuming it has absorptivity at that wavelength and direction.

And once thermal radiation is absorbed it must heat the body, or slow down a loss of heat which is taking place. It cannot have no effect. This would be contrary to the first law of thermodynamics.

Two bodies at different temperatures in proximity both radiate towards each other. Heat flow is determined by the net effect. As standard textbooks indicate:

 

From "Fundamentals of Heat and Mass Transfer, 6th edition", Incropera and DeWitt (2007)

From "Fundamentals of Heat and Mass Transfer, 6th edition", Incropera and DeWitt (2007)

 

Why the Original Misconception?

I think that the original comment about two bodies with the same temperature being unable to heat each other is an easy misconception for two reasons:

First, the most likely mental image immediately conjured up is of two pots of water at say 50ºC. When these two pots of water are mixed together the temperature is obviously still at 50ºC.

Second, the two stars are probably pictured as already in equilibrium at the original temperature. Well, if that’s the case then nothing will change. The change only occurs when they are brought closer together and so the mutual radiation from each has a slight increase on the temperature of the other.

It’s just my guess. But what actually happens in the thought experiment probably isn’t intuitively obvious.

Conclusion

When two bodies have an energy source which has created a constant surface temperature and they are subsequently brought into proximity with each other, there will be an increase in each other’s temperature. But no thermal runaway takes place, they just reach a new equilibrium.

Basic thermodynamics explains that bodies emit thermal radiation according to temperature (to the fourth power) and according to emissivity. Not according to the temperature of a different body that might happen to absorb this radiation.

And basic thermodynamics also explains that bodies absorb thermal radiation according to their absorptivity at the wavelengths (and directions) of the incident radiation. Not according to the temperature (or any other properties) of the originating body.

Therefore, there is no room in this theory for the crazy idea that colder bodies have no effect on hotter bodies. To demonstrate the opposite, the interested student would have to find a flaw in one of the two basic elements of thermodynamics described above. And just a note, there’s no point reciting a mantra (e.g., “The second law says this doesn’t happen”) upon reading this. Instead, be constructive. Explain what happens to the emitting body and the absorbing body with reference to these elementary thermodynamics theories.

Update – now that one advocate has given some explanation, a new article: Intelligent Materials and the Imaginary Second Law of Thermodynamics

Notes

1. I said earlier: “If this star absorbs thermal radiation from elsewhere, it must emit more radiation or its temperature will rise. If its temperature rises then it will radiate more energy.” Strictly speaking when radiation is absorbed it might go into other forms of energy. For example, if ice receives incident radiation it may melt, and all of the heat is absorbed into changing the state of the ice to water, not to increasing the temperature.

2. Incident radiation can also be transmitted, e.g. through a thin layer of glass, or through a given concentration of CO2, but this won’t be the case with radiation into a body like a star. The total of reflected energy plus absorbed energy plus transmitted energy has to equal the value of the incident radiation.

3. The Stefan-Boltzmann equation is the integral of the Planck function across all wavelengths and directions:

 

Spectral Intensity, Planck

Spectral Intensity, Planck

 

Where h, c0 and k are constants, T is temperature and λ is the wavelength.

The Planck function describes how spectral intensity changes with wavelength (or frequency) for a blackbody. If the emissivity as a function of wavelength is known it can be used in conjunction with the Planck function to determine the actual flux.

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More on climate basics.. Why is the lower atmosphere – the troposphere – like it is?

 

Atmospheric Temperature & Pressure Profile, Bigg (2005)

Atmospheric Temperature & Pressure Profile, Bigg (2005)

 

Pressure

The pressure vs altitude relationship is the first point to understand. Notice that (in the graphic above) the left vertical axis – height – is linear, while the right hand corresponding vertical axis – pressure – is logarithmic. Here is one sample atmospheric profile:

 

Pressure vs Height, Taylor (2005)

Pressure vs Height, Taylor (2005)

 

As a “conceptual idea” to help understand this, the pressure at any level is dependent on the total weight of atmosphere above. As you go up higher in the atmosphere the weight above decreases. As the weight above decreases, the atmosphere below is less “compressed” due to the pressure and so the pressure change is not linear with altitude. There is some maths at the end for people interested.

Temperature

The temperature decreases with altitude through the troposphere. What explains this?

Firstly, the atmosphere is mostly transparent to solar radiation so the solar radiation passes straight through the atmosphere and is absorbed by the surface – whether land or sea.

Secondly, the surface heats up because of this radiation and consequently warms the lower atmosphere. What we need to understand is the dominant mechanism by which it heats the lower atmosphere.

If we calculate the movement of heat upward through the atmosphere only by radiation (the atmosphere absorbs and emits longwave radiation) we find a vertical temperature profile which doesn’t match what we observe. When the atmosphere is “optically thick”, radiation doesn’t provide a good “re-distribution” of heat. In the troposphere, if radiation was the only mechanism for moving heat, the “lapse rate” – or change of temperature with height – would be more than 10K/km.

As we go up through the troposphere the temperature decreases with altitude. This introduces terminology problems with “more than” and “less than” (especially if we are trying to avoid maths). More rigorously I could say that the temperature change would be less than -10K/km. E.g. -12K/km.

And yet, the actual environmental lapse rate is around -6.5K/km. The “environmental lapse rate” is what we observe in practice.

Now radiation is only one mechanism for moving heat – the others are conduction and convection.

Convection is a very effective mechanism for redistributing heat. The sun heats the earth’s surface (through the almost transparent atmosphere) – the earth’s surface heats the lowest levels of the atmosphere via conduction and convection. What happens to air that is heated? If air heats it expands, and if it expands then its density becomes lower and so it will rise. The first law of thermodynamics – conservation of energy – says that if there is no change in energy then work done by a parcel of air in expanding must equal the change in heat.

This means that for dry air we can easily calculate the temperature change as air rises. The adiabatic lapse rate of dry air is -9.8K/km (=-9.8°C/km).

Calculating the value for moist air is not so simple (but is still basic physics) and depends on the humidity.

First, let’s use the dry lapse rate to consider what might happen in the atmosphere. Suppose the temperature profile has been determined by radiative equilibrium, and is therefore more than 10K/km.

So if the surface is 15°C, then 1km up the temperature will be less than 5°C, and 2km up the temperature will be less than -5°C.

If a parcel of dry air at the surface moves upward 1km then as a result of the change in energy in expanding it will reach a temperature of just over 5°C. It will be warmer than the equilibrium profile that has been established by radiation. This means it will be less dense than the surrounding air and so it will keep on rising.

Therefore, in practice, any dry air which is slightly perturbed vertically will find itself warmer than the surrounding air and will keep on rising.

So convection dominates the temperature profile of the lower atmosphere. If radiative equilibrium dominated, convection would quickly take over – because it is more effective at moving heat in the troposphere (a different story in the stratosphere).

Now let’s consider humid air. As air cools it can hold less water vapor. So water vapor will condense, thereby releasing heat. Therefore, the more humid the air, the warmer it will be at higher altitudes (because of release of latent heat). And so, humid air has a lapse rate which is “less negative” than dry air. This value can be as “low” as -4K/km in the tropics.

And on average the “environmental” lapse rate is -6.5K/km.

Conclusion

Convection determines the temperature profile in the troposphere. But radiation is the only mechanism for moving heat into and out of the earth’s climate system.

Radiation is also still very important in moving heat from the surface as can be seen in Sensible Heat, Latent Heat and Radiation.

It’s common to see “criticisms” on blogs that somehow “climate science has ignored convection and latent heat”. Atmospheric physics 101 always works through these basics to explain the temperature profile of the troposphere.

Convection, latent heat and radiation are all important movers of heat from the surface into the atmosphere. And in the case of radiation, it is also an important mover of heat back to the surface from the atmosphere.

But convection is what determines the actual temperature profile of the lower atmosphere – the troposphere.

Maths of Pressure Changes

To understand pressure vs altitude we use the hydrostatic balance equation.

The change in pressure across a small vertical “slice” of the atmosphere:

dp = -ρg.dz

The ideal gas equation says:

PV = nRT

and

ρ = M/V

so

dp/p = -dz/H, where H is the scale height, or H=RT/mg

Therefore:

H is dependent on temperature and therefore on the altitude, but as a very rough and ready approximation H doesn’t change too much. At the surface H = 8.5km and at the top of the mesosphere, H= 5.8km. The value of H tells us the change in altitude needed to reduce p (pressure) to 1/e (36%) of its original value.

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Many questions have recently been asked about the relative importance of various mechanisms for moving heat to and from the surface, so this article covers a few basics.

One Fine Day – the Radiation Components

 

Surface Radiation - clear day and cloudy day, from Robinson (1999)

Surface Radiation - clear day and cloudy day, from Robinson (1999)

 

I added some color to help pick out the different elements, note that temperature variation is also superimposed on the graph (on its own axis). The blue line is net longwave radiation.

Not so easy to see with the size of graphic, here they are expanded:

 

Clear sky

Clear sky

 

 

Cloudy sky

Cloudy sky

 

Note that the night-time is not shown, which is why the net radiation is almost always positive. You can see that the downward longwave radiation measured from the sky (in clear violation of the Imaginary Second Law of Thermodynamics) doesn’t change very much – equally so for the upwards longwave radiation from the ground. You can see the terrestrial (upwards longwave) radiation follows the temperature changes – as you would expect.

Sensible and Latent Heat

The energy change at the surface is the sum of:

  • Net radiation
  • “Sensible” heat
  • Latent heat
  • Heat flux into the ground

“Sensible” heat is that caused by conduction and convection. For example, with a warm surface and a cooler atmosphere, at the boundary layer heat will be conducted into the atmosphere and then convection will move the heat higher up into the atmosphere.

Latent heat is the heat moved by water evaporating and condensing higher up in the atmosphere. Heat is absorbed in evaporation and released by condensation – so the result is a movement of heat from the surface to higher levels in the atmosphere.

Heat flux into the ground is usually low, except into water.

 

Surface Heat Components in 3 Locations, Robinson (1999)

Surface Heat Components in 3 Locations, Robinson (1999)

 

All of these observations were made under clear skies in light to moderate wind conditions.

Note the low latent heat for the dry lake – of course.

The negative sensible heat in Arizona (2nd graphic) is because it is being drawn from the surface to evaporate water. It is more usual to see positive sensible heat during the daytime as the surface warms the lower levels of the atmosphere.

The latent heat is higher in Arizona than Wisconsin because of the drier air in Arizona (lower relative humidity).

The ratio of sensible heat to latent heat is called the Bowen ratio and the physics of the various processes mean that this ratio is kept to a minimum – a moist surface will hardly increase in temperature while evaporation is occurring, but once it has dried out there will be a rapid rise in temperature as the sensible heat flux takes over.

Heat into the Ground

 

Temperature at two depths in soil - annual variation, Robinson (1999)

Temperature at two depths in soil - annual variation, Robinson (1999)

 

We can see that heat doesn’t get very far into soil – because it is not a good conductor of heat.

Here is a useful table of properties of various substances:

The rate of heat penetration (e.g. into the soil) is dependent on the thermal diffusivity. This is a combination of two factors – the thermal conductivity (how well heat is conducted through the substance) divided by the heat capacity (how much heat it takes to increase the temperature of the substance).

The lower the value of the thermal diffusivity the lower the temperature rise further into the substance. So heat doesn’t get very far into dry sand, or still water. But it does get 10x further into wet soil (correction thanks to Nullius in Verba- really it gets 3x further into wet soil because “Thickness penetrated is proportional to the square root of diffusivity times time” – and I didn’t just take his word for it..)

Why is still water so similar to dry sand? Water has 4x the ability to conduct heat, but also it takes almost 4x as much heat to lift the temperature of water by 1°C.

Note that stirred water is a much better conductor of heat – due to convection. The same applies to air, even more so – “stirred” air (= moving air) conducts heat a million times more effectively than still air.

Temperature Profiles Throughout a 24-Hour Period

 

Temperature profiles throughout the day, Robinson (1999)

Temperature profiles throughout the day, Robinson (1999)

 

I’ll cover more about temperature profiles in a later article about why the troposphere has the temperature profile it does.

During the day the ground is being heated up by the sun and by the longwave radiation from the atmosphere. Once the sun sets, the ground cools faster and starts to take the lower levels of the atmosphere with it.

Conclusion

Just some basic measurements of the various components that affect the surface temperature to help establish their relative importance.

Note: All of the graphics were taken from Contemporary Climatology by Peter Robinson and Ann Henderson-Sellers (1999)

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